Stereodivergent synthesis of the first bis(cyclobutane) γ-dipeptides and mixed γ-oligomers

Jordi Aguilera, Albertina G. Moglioni, Graciela Y. Moltrasio, Rosa M. Ortuño

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Resum

Diastereomeric bis(cyclobutane) γ-dipeptides, a new class of γ-peptides, have been synthesized efficiently from both enantiomers of conveniently protected 3-amino-2,2-dimethyl-1-carboxylic acid. These amino acids have been prepared in very good overall yields through enantiodivergent synthetic routes starting from (-)-cis-pinononic acid. Mixed γ-oligomers have also been prepared from GABA and cyclobutane residues. © 2008 Elsevier Ltd. All rights reserved.
Idioma originalAnglès
Pàgines (de-a)302-308
RevistaTetrahedron Asymmetry
Volum19
Número3
DOIs
Estat de la publicacióPublicada - 19 de febr. 2008

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