Spectroscopic properties and photochemical behaviour of polymers with covalently bound tris(bipyridine)ruthenium(II) complex. Use of a hydrophilic chain as spacer

J. L. Bourdelande; C. Campà; J. Font; P. de March

doi:10.1016/0014-3057(89)90075-X

Spectroscopic properties and photochemical behaviour of polymers with covalently bound tris(bipyridine)ruthenium(II) complex. Use of a hydrophilic chain as spacer

J. L. Bourdelande, C. Campà, J. Font, P. de March

Departament de Química

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The synthesis of a tris(bipyridine)ruthenium(II) complex, covalently bound through a polyethoxylated chain to an insoluble polymer is described. The spectroscopic properties of several Ru(bpy)32+ complexes anchored to insoluble polystyrene supports, and of the monomeric complex are compared and shown to be very similar. Methyl viologen luminescence quenching studies of the excited state of the polymer show behaviour different from that of monomeric Ru(bpy)32+. © 1989.

Idioma original	Anglès
Pàgines (de-a)	197-202
Revista	European Polymer Journal
Volum	25
Número	2
DOIs	https://doi.org/10.1016/0014-3057(89)90075-X
Estat de la publicació	Publicada - 1 de gen. 1989

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10.1016/0014-3057(89)90075-X

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title = "Spectroscopic properties and photochemical behaviour of polymers with covalently bound tris(bipyridine)ruthenium(II) complex. Use of a hydrophilic chain as spacer",

abstract = "The synthesis of a tris(bipyridine)ruthenium(II) complex, covalently bound through a polyethoxylated chain to an insoluble polymer is described. The spectroscopic properties of several Ru(bpy)32+ complexes anchored to insoluble polystyrene supports, and of the monomeric complex are compared and shown to be very similar. Methyl viologen luminescence quenching studies of the excited state of the polymer show behaviour different from that of monomeric Ru(bpy)32+. {\textcopyright} 1989.",

author = "Bourdelande, {J. L.} and C. Camp{\`a} and J. Font and {de March}, P.",

year = "1989",

month = jan,

day = "1",

doi = "10.1016/0014-3057(89)90075-X",

language = "English",

volume = "25",

pages = "197--202",

journal = "European Polymer Journal",

issn = "0014-3057",

publisher = "Elsevier Limited",

number = "2",

}

Spectroscopic properties and photochemical behaviour of polymers with covalently bound tris(bipyridine)ruthenium(II) complex. Use of a hydrophilic chain as spacer. / Bourdelande, J. L.; Campà, C.; Font, J. et al.
In: European Polymer Journal, Vol. 25, Núm. 2, 01.01.1989, pàg. 197-202.

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TY - JOUR

T1 - Spectroscopic properties and photochemical behaviour of polymers with covalently bound tris(bipyridine)ruthenium(II) complex. Use of a hydrophilic chain as spacer

AU - Bourdelande, J. L.

AU - Campà, C.

AU - Font, J.

AU - de March, P.

PY - 1989/1/1

Y1 - 1989/1/1

N2 - The synthesis of a tris(bipyridine)ruthenium(II) complex, covalently bound through a polyethoxylated chain to an insoluble polymer is described. The spectroscopic properties of several Ru(bpy)32+ complexes anchored to insoluble polystyrene supports, and of the monomeric complex are compared and shown to be very similar. Methyl viologen luminescence quenching studies of the excited state of the polymer show behaviour different from that of monomeric Ru(bpy)32+. © 1989.

AB - The synthesis of a tris(bipyridine)ruthenium(II) complex, covalently bound through a polyethoxylated chain to an insoluble polymer is described. The spectroscopic properties of several Ru(bpy)32+ complexes anchored to insoluble polystyrene supports, and of the monomeric complex are compared and shown to be very similar. Methyl viologen luminescence quenching studies of the excited state of the polymer show behaviour different from that of monomeric Ru(bpy)32+. © 1989.

U2 - 10.1016/0014-3057(89)90075-X

DO - 10.1016/0014-3057(89)90075-X

M3 - Article

SN - 0014-3057

VL - 25

SP - 197

EP - 202

JO - European Polymer Journal

JF - European Polymer Journal

IS - 2

ER -

Spectroscopic properties and photochemical behaviour of polymers with covalently bound tris(bipyridine)ruthenium(II) complex. Use of a hydrophilic chain as spacer

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