TY - JOUR
T1 - Single-Crystal-to-Single-Crystal Postsynthetic Modification of a Metal-Organic Framework via Ozonolysis
AU - Albalad, Jorge
AU - Xu, Heng
AU - Gándara, Felipe
AU - Haouas, Mohamed
AU - Martineau-Corcos, Charlotte
AU - Mas-Ballesté, Rubén
AU - Barnett, Sarah A.
AU - Juanhuix, Judith
AU - Imaz, Inhar
AU - Maspoch, Daniel
PY - 2018/2/14
Y1 - 2018/2/14
N2 - © 2018 American Chemical Society. We describe solid-gas phase, single-crystal-to-single-crystal, postsynthetic modifications of a metal-organic framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.
AB - © 2018 American Chemical Society. We describe solid-gas phase, single-crystal-to-single-crystal, postsynthetic modifications of a metal-organic framework (MOF). Using ozone, we quantitatively transformed the olefin groups of a UiO-66-type MOF into 1,2,4-trioxolane rings, which we then selectively converted into either aldehydes or carboxylic acids.
UR - https://www.scopus.com/pages/publications/85042053614
U2 - 10.1021/jacs.7b12913
DO - 10.1021/jacs.7b12913
M3 - Article
SN - 0002-7863
VL - 140
SP - 2028
EP - 2031
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 6
ER -