TY - JOUR
T1 - Self-organized spatio-temporal micropatterning in ferromagnetic Co-In films
AU - Golvano-Escobal, Irati
AU - Özkale, Berna
AU - Suriñach, Santiago
AU - Baró, Maria Dolors
AU - Dobrovolska, Tsvetina
AU - Krastev, Ivan
AU - Pané, Salvador
AU - Sort, Jordi
AU - Pellicer, Eva
PY - 2014/10/21
Y1 - 2014/10/21
N2 - © the Partner Organisations 2014. Cobalt-indium (Co-In) heterogeneous films, featuring spatio-temporal patterns, have been electrodeposited in a chloride-citrate electrolyte. The Co content can be tuned from 25 at% to 90 at% by varying the applied current density between -10 and -30 mA cm-2. The spatio-temporal patterns consist of alternated dark and bright belts, which define micron-sized waves, targets and spirals. Cross-sectional images indicate layer-by-layer growth. Several crystallographic phases (hexagonal close-packed Co, face-centered cubic Co, tetragonal In and tetragonal CoIn3) are identified in the corresponding X-ray diffractograms. The films exhibit a combination of large hardness with relatively large Young's modulus and a soft-magnetic behaviour with tunable saturation magnetisation and coercivity (HC) values, mostly depending on the Co content and the effective magnetic anisotropy. The film with 90 at% Co shows the highest in-plane HC (275 Oe) and a squareness ratio close to 1. Magnetic force microscopy observations reveal that the self-patterning is not only topographic but also magnetic. These results demonstrate that the electrodeposition of spatio-temporal structures is a simple method to grow magnetically patterned films, over large areas, in a rapid and inexpensive way. This procedure is highly attractive for the implementation of new types of magnetic sensors, encoding magnetic stripes or even magnetic recording media. This journal is
AB - © the Partner Organisations 2014. Cobalt-indium (Co-In) heterogeneous films, featuring spatio-temporal patterns, have been electrodeposited in a chloride-citrate electrolyte. The Co content can be tuned from 25 at% to 90 at% by varying the applied current density between -10 and -30 mA cm-2. The spatio-temporal patterns consist of alternated dark and bright belts, which define micron-sized waves, targets and spirals. Cross-sectional images indicate layer-by-layer growth. Several crystallographic phases (hexagonal close-packed Co, face-centered cubic Co, tetragonal In and tetragonal CoIn3) are identified in the corresponding X-ray diffractograms. The films exhibit a combination of large hardness with relatively large Young's modulus and a soft-magnetic behaviour with tunable saturation magnetisation and coercivity (HC) values, mostly depending on the Co content and the effective magnetic anisotropy. The film with 90 at% Co shows the highest in-plane HC (275 Oe) and a squareness ratio close to 1. Magnetic force microscopy observations reveal that the self-patterning is not only topographic but also magnetic. These results demonstrate that the electrodeposition of spatio-temporal structures is a simple method to grow magnetically patterned films, over large areas, in a rapid and inexpensive way. This procedure is highly attractive for the implementation of new types of magnetic sensors, encoding magnetic stripes or even magnetic recording media. This journal is
U2 - 10.1039/c4tc01316f
DO - 10.1039/c4tc01316f
M3 - Article
SN - 2050-7534
VL - 2
SP - 8259
EP - 8269
JO - Journal of Materials Chemistry C
JF - Journal of Materials Chemistry C
IS - 39
ER -