Rhodium catalyzed asymmetric hydroformylation of vinylarenes with a diphosphite ligand forming a large chelating ring

Z. Freixa, J. C. Bayón

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Resum

A rhodium complex containing a sixteen membered chelated diphosphite, with the appropriate combination of stereogenic centers, produces ee's above 70% in the hydroformylation of vinylarenes, while a related diastereo-isomeric ligand renders very low ee's because it does not form a chelated species.
Idioma originalAnglès
Pàgines (de-a)2067-2068
RevistaJournal of the Chemical Society, Dalton Transactions
Número14
DOIs
Estat de la publicacióPublicada - 9 d’ag. 2001

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