Rh(I) and Ir(I) dithioether complexes and their application in the hydrogenation of olefins

Anna Gomis; Gemma Net; Aurora Ruiz; Carmen Claver; Angel Alvarez-Larena

doi:10.1016/S0020-1693(01)00623-5

Rh(I) and Ir(I) dithioether complexes and their application in the hydrogenation of olefins

Anna Gomis, Gemma Net, Aurora Ruiz, Carmen Claver, Angel Alvarez-Larena

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Mononuclear complexes [M(cod)(RS(CH2)nSR)]BF4 (M = Rh, Ir; n = 2-4)) were synthesized and characterized. The crystal structure of [Rh(cod){(CH3)2CHS(CH2)4SCH(CH 3)2}]BF4 was determined by X-ray diffraction. The iridium complexes are catalytically active precursors in the hydrogenation of olefins. The effect of the length of the backbone between the two sulfur atoms and the group R bonded to sulfur was studied in the hydrogenation of itaconic acid and 1-hexene. © 2001 Elsevier Science B.V. All rights reserved.

Idioma original	Anglès
Pàgines (de-a)	58-64
Revista	Inorganica Chimica Acta
Volum	325
Número	1-2
DOIs	https://doi.org/10.1016/S0020-1693(01)00623-5
Estat de la publicació	Publicada - 3 de des. 2001

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10.1016/S0020-1693(01)00623-5

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@article{90d3e58d32144292be43008466e44ee8,

title = "Rh(I) and Ir(I) dithioether complexes and their application in the hydrogenation of olefins",

abstract = "Mononuclear complexes [M(cod)(RS(CH2)nSR)]BF4 (M = Rh, Ir; n = 2-4)) were synthesized and characterized. The crystal structure of [Rh(cod)\{(CH3)2CHS(CH2)4SCH(CH 3)2\}]BF4 was determined by X-ray diffraction. The iridium complexes are catalytically active precursors in the hydrogenation of olefins. The effect of the length of the backbone between the two sulfur atoms and the group R bonded to sulfur was studied in the hydrogenation of itaconic acid and 1-hexene. {\textcopyright} 2001 Elsevier Science B.V. All rights reserved.",

keywords = "Dithioether complexes, Hydrogenation of olefins, Rhodium and iridium complexes, S-ligands",

author = "Anna Gomis and Gemma Net and Aurora Ruiz and Carmen Claver and Angel Alvarez-Larena",

year = "2001",

month = dec,

day = "3",

doi = "10.1016/S0020-1693(01)00623-5",

language = "English",

volume = "325",

pages = "58--64",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier BV",

number = "1-2",

}

TY - JOUR

T1 - Rh(I) and Ir(I) dithioether complexes and their application in the hydrogenation of olefins

AU - Gomis, Anna

AU - Net, Gemma

AU - Ruiz, Aurora

AU - Claver, Carmen

AU - Alvarez-Larena, Angel

PY - 2001/12/3

Y1 - 2001/12/3

N2 - Mononuclear complexes [M(cod)(RS(CH2)nSR)]BF4 (M = Rh, Ir; n = 2-4)) were synthesized and characterized. The crystal structure of [Rh(cod){(CH3)2CHS(CH2)4SCH(CH 3)2}]BF4 was determined by X-ray diffraction. The iridium complexes are catalytically active precursors in the hydrogenation of olefins. The effect of the length of the backbone between the two sulfur atoms and the group R bonded to sulfur was studied in the hydrogenation of itaconic acid and 1-hexene. © 2001 Elsevier Science B.V. All rights reserved.

AB - Mononuclear complexes [M(cod)(RS(CH2)nSR)]BF4 (M = Rh, Ir; n = 2-4)) were synthesized and characterized. The crystal structure of [Rh(cod){(CH3)2CHS(CH2)4SCH(CH 3)2}]BF4 was determined by X-ray diffraction. The iridium complexes are catalytically active precursors in the hydrogenation of olefins. The effect of the length of the backbone between the two sulfur atoms and the group R bonded to sulfur was studied in the hydrogenation of itaconic acid and 1-hexene. © 2001 Elsevier Science B.V. All rights reserved.

KW - Dithioether complexes

KW - Hydrogenation of olefins

KW - Rhodium and iridium complexes

KW - S-ligands

UR - https://www.scopus.com/pages/publications/0035803143

U2 - 10.1016/S0020-1693(01)00623-5

DO - 10.1016/S0020-1693(01)00623-5

M3 - Article

SN - 0020-1693

VL - 325

SP - 58

EP - 64

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 1-2

ER -

Rh(I) and Ir(I) dithioether complexes and their application in the hydrogenation of olefins

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