Reductively activated "polar" nucleophilic aromatic substitution of pentafluoronitrobenzene. The S<inf>RN</inf>2 hypothesis revisited

Jorge Marquet; Ziqi Jiang; Iluminada Gallardo; Anna Batlle; Eduard Cayón

doi:10.1016/S0040-4039(00)73566-0

Reductively activated "polar" nucleophilic aromatic substitution of pentafluoronitrobenzene. The S<inf>RN</inf>2 hypothesis revisited

Jorge Marquet, Ziqi Jiang, Iluminada Gallardo, Anna Batlle, Eduard Cayón

Departament de Química

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Resum

The reactions between pentafluoronitrobenzene and several nucleophiles, in aqueous media, can be photo- and electro-stimulated (reductively). Our results indicate we are in the presence of a chain reaction type that includes direct attack of the nucleophile on the radical anion of the substrate. © 1993.

Idioma original	Anglès
Pàgines (de-a)	2801-2804
Revista	Tetrahedron Letters
Volum	34
Número	17
DOIs	https://doi.org/10.1016/S0040-4039(00)73566-0
Estat de la publicació	Publicada - 23 d’abr. 1993

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10.1016/S0040-4039(00)73566-0

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abstract = "The reactions between pentafluoronitrobenzene and several nucleophiles, in aqueous media, can be photo- and electro-stimulated (reductively). Our results indicate we are in the presence of a chain reaction type that includes direct attack of the nucleophile on the radical anion of the substrate. {\textcopyright} 1993.",

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T1 - Reductively activated "polar" nucleophilic aromatic substitution of pentafluoronitrobenzene. The SRN2 hypothesis revisited

AU - Marquet, Jorge

AU - Jiang, Ziqi

AU - Gallardo, Iluminada

AU - Batlle, Anna

AU - Cayón, Eduard

PY - 1993/4/23

Y1 - 1993/4/23

N2 - The reactions between pentafluoronitrobenzene and several nucleophiles, in aqueous media, can be photo- and electro-stimulated (reductively). Our results indicate we are in the presence of a chain reaction type that includes direct attack of the nucleophile on the radical anion of the substrate. © 1993.

AB - The reactions between pentafluoronitrobenzene and several nucleophiles, in aqueous media, can be photo- and electro-stimulated (reductively). Our results indicate we are in the presence of a chain reaction type that includes direct attack of the nucleophile on the radical anion of the substrate. © 1993.

U2 - 10.1016/S0040-4039(00)73566-0

DO - 10.1016/S0040-4039(00)73566-0

M3 - Article

SN - 0040-4039

VL - 34

SP - 2801

EP - 2804

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 17

ER -

Reductively activated "polar" nucleophilic aromatic substitution of pentafluoronitrobenzene. The S<inf>RN</inf>2 hypothesis revisited

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