TY - JOUR
T1 - Reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with dimethylphenylphosphine. Synthesis and structure of [FeCo(CO)4(μ-CO)-(PMe2Ph)2(μ-CH=CH2)], an electronically unbalanced iron-cobalt complex
AU - Moldes, Isabel
AU - Ros, Josep
AU - Yañez, Ramón
AU - Mathieu, René
AU - Solans, Xavier
AU - Font-Bardí, Mercé
PY - 1988/12/1
Y1 - 1988/12/1
N2 - The reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with PMe2Ph leads to complexes [FeCo(CO)6(PMe2Ph)(μ-CH=CPhH)] and [FeCo(CO)5(PMe2Ph)2(μ-CH=CRH)]. The disubstituted compounds contain two PMe2Ph ligands linked to iron and two bridging ligands, carbonyl and vinyl. The structure of [FeCo(CO)4(μ-CO)(PMe2Ph)2(μ-CH=CH 2)] has been solved by X-ray diffraction methods.
AB - The reaction of [FeCo(CO)7(μ-CH=CRH)] (R = H or Ph) with PMe2Ph leads to complexes [FeCo(CO)6(PMe2Ph)(μ-CH=CPhH)] and [FeCo(CO)5(PMe2Ph)2(μ-CH=CRH)]. The disubstituted compounds contain two PMe2Ph ligands linked to iron and two bridging ligands, carbonyl and vinyl. The structure of [FeCo(CO)4(μ-CO)(PMe2Ph)2(μ-CH=CH 2)] has been solved by X-ray diffraction methods.
U2 - 10.1039/DT9880001417
DO - 10.1039/DT9880001417
M3 - Article
SN - 1472-7773
SP - 1417
EP - 1419
JO - Journal of the Chemical Society, Dalton Transactions
JF - Journal of the Chemical Society, Dalton Transactions
IS - 5
ER -