Resum
The oxidative addition of C<inf>sp</inf><sup>2</sup>-Br or C <inf>sp</inf><sup>2</sup>-I bonds to gold(i) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(iii) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish. © The Royal Society of Chemistry.
Idioma original | Anglès |
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Pàgines (de-a) | 1533-1536 |
Revista | Chemical Communications |
Volum | 50 |
Número | 13 |
DOIs | |
Estat de la publicació | Publicada - 14 de febr. 2014 |