Rationale for the sluggish oxidative addition of aryl halides to Au(I)

Madeleine Livendahl, Charles Goehry, Feliu Maseras, Antonio M. Echavarren

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Resum

The oxidative addition of C<inf>sp</inf><sup>2</sup>-Br or C <inf>sp</inf><sup>2</sup>-I bonds to gold(i) does not take place even under very favorable intramolecular conditions that could form five- or six-membered gold(iii) metallacycles. DFT calculations reveal that although this process could be feasible thermodynamically, it is kinetically very sluggish. © The Royal Society of Chemistry.
Idioma originalAnglès
Pàgines (de-a)1533-1536
RevistaChemical Communications
Volum50
Número13
DOIs
Estat de la publicacióPublicada - 14 de febr. 2014

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