TY - JOUR
T1 - Protection strategies for directionally-controlled synthesis of previously inaccessible metal-organic polyhedra (MOPs): The cases of carboxylate: The amino-functionalised Rh(ii)-MOPs
T2 - the cases of carboxylate- and amino-functionalised Rh(ii)-MOPs
AU - Albalad, Jorge
AU - Carné-Sánchez, Arnau
AU - Grancha, Thais
AU - Hernández-López, Laura
AU - Maspoch, Daniel
PY - 2019/11/4
Y1 - 2019/11/4
N2 - This journal is © The Royal Society of Chemistry. Herein we report that strategic use of protecting groups in coordination reactions enables directional inhibition that leads to synthesis of highly functionalised metal-organic polyhedra (MOPs), rather than of the extended coordination networks. Using this approach, we functionalised two new porous cuboctahedral Rh(ii)-based MOPs with 24 peripheral carboxylic acid groups or 24 peripheral amino groups.
AB - This journal is © The Royal Society of Chemistry. Herein we report that strategic use of protecting groups in coordination reactions enables directional inhibition that leads to synthesis of highly functionalised metal-organic polyhedra (MOPs), rather than of the extended coordination networks. Using this approach, we functionalised two new porous cuboctahedral Rh(ii)-based MOPs with 24 peripheral carboxylic acid groups or 24 peripheral amino groups.
UR - http://www.mendeley.com/research/protection-strategies-directionallycontrolled-synthesis-previously-inaccessible-metalorganic-polyhed
U2 - 10.1039/c9cc07083d
DO - 10.1039/c9cc07083d
M3 - Article
C2 - 31591620
SN - 1359-7345
VL - 55
SP - 12785
EP - 12788
JO - Chemical Communications
JF - Chemical Communications
IS - 85
ER -