Production of high purity hydrogen by ethanol steam reforming in membrane reactor

E. Yu Mironova; M. M. Ermilova; N. V. Orekhova; D. N. Muraviev; A. B. Yaroslavtsev

doi:10.1016/j.cattod.2014.01.014

Production of high purity hydrogen by ethanol steam reforming in membrane reactor

E. Yu Mironova, M. M. Ermilova, N. V. Orekhova, D. N. Muraviev, A. B. Yaroslavtsev

Departament de Química

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Production of hydrogen in the course of ethanol steam reforming (ESR) on bimetallic Pt-Ni and Pt-Ru nanocatalysts supported on detonation nanodiamonds (DND) was studied in conventional and membrane reactors. The highest hydrogen yield and purity were achieved in the case of Pt-Ru/DND catalysts at total metal content of 0.3% and atomic Pt/Ru ratio of 9/1. It is shown that realization of ESR process in the membrane reactor with simultaneous hydrogen removal through the Pd-Ru membrane produces hydrogen of high purity, free of any other gaseous products. © 2014 Elsevier B.V.

Idioma original	Anglès
Pàgines (de-a)	64-69
Revista	Catalysis Today
Volum	236
Número	PART A
DOIs	https://doi.org/10.1016/j.cattod.2014.01.014
Estat de la publicació	Publicada - 1 de nov. 2014

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10.1016/j.cattod.2014.01.014

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title = "Production of high purity hydrogen by ethanol steam reforming in membrane reactor",

abstract = "Production of hydrogen in the course of ethanol steam reforming (ESR) on bimetallic Pt-Ni and Pt-Ru nanocatalysts supported on detonation nanodiamonds (DND) was studied in conventional and membrane reactors. The highest hydrogen yield and purity were achieved in the case of Pt-Ru/DND catalysts at total metal content of 0.3% and atomic Pt/Ru ratio of 9/1. It is shown that realization of ESR process in the membrane reactor with simultaneous hydrogen removal through the Pd-Ru membrane produces hydrogen of high purity, free of any other gaseous products. {\textcopyright} 2014 Elsevier B.V.",

keywords = "Ethanol steam reforming, Nanodiamond-supported metal catalysts, Pd-Ru membrane reactor",

author = "Mironova, {E. Yu} and Ermilova, {M. M.} and Orekhova, {N. V.} and Muraviev, {D. N.} and Yaroslavtsev, {A. B.}",

year = "2014",

month = nov,

day = "1",

doi = "10.1016/j.cattod.2014.01.014",

language = "English",

volume = "236",

pages = "64--69",

number = "PART A",

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TY - JOUR

T1 - Production of high purity hydrogen by ethanol steam reforming in membrane reactor

AU - Mironova, E. Yu

AU - Ermilova, M. M.

AU - Orekhova, N. V.

AU - Muraviev, D. N.

AU - Yaroslavtsev, A. B.

PY - 2014/11/1

Y1 - 2014/11/1

N2 - Production of hydrogen in the course of ethanol steam reforming (ESR) on bimetallic Pt-Ni and Pt-Ru nanocatalysts supported on detonation nanodiamonds (DND) was studied in conventional and membrane reactors. The highest hydrogen yield and purity were achieved in the case of Pt-Ru/DND catalysts at total metal content of 0.3% and atomic Pt/Ru ratio of 9/1. It is shown that realization of ESR process in the membrane reactor with simultaneous hydrogen removal through the Pd-Ru membrane produces hydrogen of high purity, free of any other gaseous products. © 2014 Elsevier B.V.

AB - Production of hydrogen in the course of ethanol steam reforming (ESR) on bimetallic Pt-Ni and Pt-Ru nanocatalysts supported on detonation nanodiamonds (DND) was studied in conventional and membrane reactors. The highest hydrogen yield and purity were achieved in the case of Pt-Ru/DND catalysts at total metal content of 0.3% and atomic Pt/Ru ratio of 9/1. It is shown that realization of ESR process in the membrane reactor with simultaneous hydrogen removal through the Pd-Ru membrane produces hydrogen of high purity, free of any other gaseous products. © 2014 Elsevier B.V.

KW - Ethanol steam reforming

KW - Nanodiamond-supported metal catalysts

KW - Pd-Ru membrane reactor

U2 - 10.1016/j.cattod.2014.01.014

DO - 10.1016/j.cattod.2014.01.014

M3 - Article

SN - 0920-5861

VL - 236

SP - 64

EP - 69

JO - Catalysis Today

JF - Catalysis Today

IS - PART A

ER -

Production of high purity hydrogen by ethanol steam reforming in membrane reactor

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