Preparation of homochiral 9-anthryl-tert-butylcarbinol. The configurational and conformational NMR study of its carbamate derivatives

Maria de Moragas, Adriana Port, Xavier Sánchez-Ruiz, Carlos Jaime, Christian Roussel, Albert Virgili

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Resum

The homochiral carbamates of 9-anthryl-tert-butylcarbinol were prepared and their conformational equilibrium was studied. The absolute configuration was determined by comparison of the NMR data with MM calculations. The enantiomers of the alcohol were obtained after chromatographic separation of carbamate derivatives and their hydrolysis. The same homochiral alcohols were prepared by direct chiral column chromatography. © 1995.
Idioma originalAnglès
Pàgines (de-a)1307-1310
RevistaTetrahedron: asymmetry
Volum6
Número6
DOIs
Estat de la publicacióPublicada - 1 de gen. 1995

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