TY - JOUR
T1 - Preparation of enantiomers of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene. Conformational study and their behaviour as chiral solvating agents
AU - Port, Adriana
AU - Virgili, Albert
AU - Jaime, Carlos
PY - 1996/1/1
Y1 - 1996/1/1
N2 - Homochiral forms of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene were prepared by hydrolysis of crystallised diastereomeric salts of mandelic acid. The activity as chiral solvating agent was tested in the presence of several alcohols and acids. A boat conformation of the central ring was demonstrated by NMR studies and MM3 calculations.
AB - Homochiral forms of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene were prepared by hydrolysis of crystallised diastereomeric salts of mandelic acid. The activity as chiral solvating agent was tested in the presence of several alcohols and acids. A boat conformation of the central ring was demonstrated by NMR studies and MM3 calculations.
U2 - 10.1016/0957-4166(96)00146-2
DO - 10.1016/0957-4166(96)00146-2
M3 - Article
SN - 0957-4166
VL - 7
SP - 1295
EP - 1302
JO - Tetrahedron Asymmetry
JF - Tetrahedron Asymmetry
IS - 5
ER -