Preparation of enantiomers of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene. Conformational study and their behaviour as chiral solvating agents

Adriana Port, Albert Virgili, Carlos Jaime

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Resum

Homochiral forms of 9-(1-amino-2,2-dimethylpropyl)-9,10-dihydroanthracene were prepared by hydrolysis of crystallised diastereomeric salts of mandelic acid. The activity as chiral solvating agent was tested in the presence of several alcohols and acids. A boat conformation of the central ring was demonstrated by NMR studies and MM3 calculations.
Idioma originalAnglès
Pàgines (de-a)1295-1302
RevistaTetrahedron Asymmetry
Volum7
Número5
DOIs
Estat de la publicacióPublicada - 1 de gen. 1996

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