TY - JOUR
T1 - Preparation of a hybrid organic-inorganic material containing macrocyclic triolefinic 15-membered palladium(0) complex: Catalytic activity in Suzuki cross-coupling and butadiene telomerization reactions
AU - Blanco, Belén
AU - Brissart, Marina
AU - Moreno-Mañas, Marcial
AU - Pleixats, Roser
AU - Mehdi, Ahmad
AU - Reyé, Catherine
AU - Bouquillon, Sandrine
AU - Hénin, Françoise
AU - Muzart, Jacques
PY - 2006/1/6
Y1 - 2006/1/6
N2 - The synthesis of a bis-silylated 15-membered azatriolefinic macrocycle is described as well as its co-gelification with tetraethyl orthosilicate. The resulting material was treated with Pd(dba)2 affording an hybrid organic-inorganic material containing macrocyclic palladium(0) complex covalently bonded to the silica matrix. The activity of this material as catalyst or precatalyst in Suzuki cross-coupling and telomerization of butadiene with methanol and phenol is presented. © 2005 Elsevier B.V. All rights reserved.
AB - The synthesis of a bis-silylated 15-membered azatriolefinic macrocycle is described as well as its co-gelification with tetraethyl orthosilicate. The resulting material was treated with Pd(dba)2 affording an hybrid organic-inorganic material containing macrocyclic palladium(0) complex covalently bonded to the silica matrix. The activity of this material as catalyst or precatalyst in Suzuki cross-coupling and telomerization of butadiene with methanol and phenol is presented. © 2005 Elsevier B.V. All rights reserved.
KW - Cross-coupling
KW - Macrocycles
KW - Palladium supported catalyst
KW - Sol-gel processes
KW - Telomerization
U2 - 10.1016/j.apcata.2005.07.062
DO - 10.1016/j.apcata.2005.07.062
M3 - Article
SN - 0926-860X
VL - 297
SP - 117
EP - 124
JO - Applied Catalysis A: General
JF - Applied Catalysis A: General
IS - 2
ER -