Preparation and study of functionalized 1,2,4-triazine derivatives of the (η6-arene)RuII (arene = benzene or p-cymene) and (η5-C<inf>5</inf>Me<inf>5</inf>)RhIII moieties

Gabriel Garcia; Isabel Solano; Gregorio Sanchez; Gregorio Lopez; Jaume Casabo; Elies Molins; Carles Miravitlles

doi:10.1016/0277-5387(94)00469-U

Preparation and study of functionalized 1,2,4-triazine derivatives of the (η6-arene)RuII (arene = benzene or p-cymene) and (η5-C<inf>5</inf>Me<inf>5</inf>)RhIII moieties

Gabriel Garcia, Isabel Solano, Gregorio Sanchez, Gregorio Lopez, Jaume Casabo, Elies Molins, Carles Miravitlles

Departament de Química

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In dichloromethane the complexes [[(η6-arene)RuCl(μ-Cl)]2] (arene- = benzene or p-cymene) and [[(η5-C5Me5)RhCl(μ-Cl)]2] react with the triazines 4-amino-6-methyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine (3-S-ATAZ), 4-amino-6-methyl-5-oxo-3-phenylamino-4,5-dihydro-1,2,4-triazine (3-PhNH-ATAZ) and 4-amino-6-methyl-5-oxo-3-amino-4,5-dihydro-1,2,4-triazine (3-NH2-ATAZ) to form the corresponding complexes [(η6-arene)RuCl(triazine)]Cl and [(η5-C5Me5)RhCl(triazine)]Cl. The new compounds have been characterized by conductance measurements and spectroscopic (IR, 1H, 13C) methods. In every case the triazine acts as a chelating bidentate ligand, which has been confirmed by a single-crystal diffraction study carried out with [(η5-C5Me5)RhCl(3-PhNH-ATAZ)]PF6·H2O. © 1995.

Idioma original	Anglès
Pàgines (de-a)	1855-1863
Revista	Polyhedron
Volum	14
Número	13-14
DOIs	https://doi.org/10.1016/0277-5387(94)00469-U
Estat de la publicació	Publicada - 1 de gen. 1995

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Garcia, G., Solano, I., Sanchez, G., Lopez, G., Casabo, J., Molins, E., & Miravitlles, C. (1995). Preparation and study of functionalized 1,2,4-triazine derivatives of the (η6-arene)RuII (arene = benzene or p-cymene) and (η5-C<inf>5</inf>Me<inf>5</inf>)RhIII moieties. Polyhedron, 14(13-14), 1855-1863. https://doi.org/10.1016/0277-5387(94)00469-U

@article{8da13a3f006347e28db70c6f13df2a79,

title = "Preparation and study of functionalized 1,2,4-triazine derivatives of the (η6-arene)RuII (arene = benzene or p-cymene) and (η5-C5Me5)RhIII moieties",

abstract = "In dichloromethane the complexes [[(η6-arene)RuCl(μ-Cl)]2] (arene- = benzene or p-cymene) and [[(η5-C5Me5)RhCl(μ-Cl)]2] react with the triazines 4-amino-6-methyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine (3-S-ATAZ), 4-amino-6-methyl-5-oxo-3-phenylamino-4,5-dihydro-1,2,4-triazine (3-PhNH-ATAZ) and 4-amino-6-methyl-5-oxo-3-amino-4,5-dihydro-1,2,4-triazine (3-NH2-ATAZ) to form the corresponding complexes [(η6-arene)RuCl(triazine)]Cl and [(η5-C5Me5)RhCl(triazine)]Cl. The new compounds have been characterized by conductance measurements and spectroscopic (IR, 1H, 13C) methods. In every case the triazine acts as a chelating bidentate ligand, which has been confirmed by a single-crystal diffraction study carried out with [(η5-C5Me5)RhCl(3-PhNH-ATAZ)]PF6·H2O. {\textcopyright} 1995.",

author = "Gabriel Garcia and Isabel Solano and Gregorio Sanchez and Gregorio Lopez and Jaume Casabo and Elies Molins and Carles Miravitlles",

year = "1995",

month = jan,

day = "1",

doi = "10.1016/0277-5387(94)00469-U",

language = "English",

volume = "14",

pages = "1855--1863",

number = "13-14",

}

Garcia, G, Solano, I, Sanchez, G, Lopez, G, Casabo, J, Molins, E & Miravitlles, C 1995, 'Preparation and study of functionalized 1,2,4-triazine derivatives of the (η6-arene)RuII (arene = benzene or p-cymene) and (η5-C<inf>5</inf>Me<inf>5</inf>)RhIII moieties', Polyhedron, vol. 14, núm. 13-14, pàg. 1855-1863. https://doi.org/10.1016/0277-5387(94)00469-U

Preparation and study of functionalized 1,2,4-triazine derivatives of the (η6-arene)RuII (arene = benzene or p-cymene) and (η5-C<inf>5</inf>Me<inf>5</inf>)RhIII moieties. / Garcia, Gabriel; Solano, Isabel; Sanchez, Gregorio et al.
In: Polyhedron, Vol. 14, Núm. 13-14, 01.01.1995, pàg. 1855-1863.

Producció científica: Contribució a revista › Article › Recerca › Avaluat per experts

TY - JOUR

T1 - Preparation and study of functionalized 1,2,4-triazine derivatives of the (η6-arene)RuII (arene = benzene or p-cymene) and (η5-C5Me5)RhIII moieties

AU - Garcia, Gabriel

AU - Solano, Isabel

AU - Sanchez, Gregorio

AU - Lopez, Gregorio

AU - Casabo, Jaume

AU - Molins, Elies

AU - Miravitlles, Carles

PY - 1995/1/1

Y1 - 1995/1/1

N2 - In dichloromethane the complexes [[(η6-arene)RuCl(μ-Cl)]2] (arene- = benzene or p-cymene) and [[(η5-C5Me5)RhCl(μ-Cl)]2] react with the triazines 4-amino-6-methyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine (3-S-ATAZ), 4-amino-6-methyl-5-oxo-3-phenylamino-4,5-dihydro-1,2,4-triazine (3-PhNH-ATAZ) and 4-amino-6-methyl-5-oxo-3-amino-4,5-dihydro-1,2,4-triazine (3-NH2-ATAZ) to form the corresponding complexes [(η6-arene)RuCl(triazine)]Cl and [(η5-C5Me5)RhCl(triazine)]Cl. The new compounds have been characterized by conductance measurements and spectroscopic (IR, 1H, 13C) methods. In every case the triazine acts as a chelating bidentate ligand, which has been confirmed by a single-crystal diffraction study carried out with [(η5-C5Me5)RhCl(3-PhNH-ATAZ)]PF6·H2O. © 1995.

AB - In dichloromethane the complexes [[(η6-arene)RuCl(μ-Cl)]2] (arene- = benzene or p-cymene) and [[(η5-C5Me5)RhCl(μ-Cl)]2] react with the triazines 4-amino-6-methyl-5-oxo-3-thioxo-2,3,4,5-tetrahydro-1,2,4-triazine (3-S-ATAZ), 4-amino-6-methyl-5-oxo-3-phenylamino-4,5-dihydro-1,2,4-triazine (3-PhNH-ATAZ) and 4-amino-6-methyl-5-oxo-3-amino-4,5-dihydro-1,2,4-triazine (3-NH2-ATAZ) to form the corresponding complexes [(η6-arene)RuCl(triazine)]Cl and [(η5-C5Me5)RhCl(triazine)]Cl. The new compounds have been characterized by conductance measurements and spectroscopic (IR, 1H, 13C) methods. In every case the triazine acts as a chelating bidentate ligand, which has been confirmed by a single-crystal diffraction study carried out with [(η5-C5Me5)RhCl(3-PhNH-ATAZ)]PF6·H2O. © 1995.

U2 - 10.1016/0277-5387(94)00469-U

DO - 10.1016/0277-5387(94)00469-U

M3 - Article

SN - 0277-5387

VL - 14

SP - 1855

EP - 1863

JO - Polyhedron

JF - Polyhedron

IS - 13-14

ER -

Preparation and study of functionalized 1,2,4-triazine derivatives of the (η<sup>6</sup>-arene)Ru<sup>II</sup> (arene = benzene or p-cymene) and (η<sup>5</sup>-C<inf>5</inf>Me<inf>5</inf>)Rh<sup>III</sup> moieties

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