Pentafluorothiophenolate derivatives of cobalt(II) and nickel(II). The molecular structure of [Ni(SC<inf>6</inf>F<inf>5</inf>)<inf>2</inf>Ph<inf>2</inf>PCH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>]

R. M. Catalá; M. E. Colsa; D. Cruz-Garritz; H. Torrens; J. L. Brianso; J. E. Piniella; G. Germain

doi:10.1007/BF01023527

Pentafluorothiophenolate derivatives of cobalt(II) and nickel(II). The molecular structure of [Ni(SC<inf>6</inf>F<inf>5</inf>)<inf>2</inf>Ph<inf>2</inf>PCH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>]

R. M. Catalá, M. E. Colsa, D. Cruz-Garritz, H. Torrens, J. L. Brianso, J. E. Piniella, G. Germain

Departament de Geologia

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The tetrahedral compounds [Co(SC6F5)2L] (L=Ph2P(CH2)nPPh2, n=1, 2 and 3) and the squareplanar compound [Ni(SC6F5)2(PhPCH2CH2PPh2)] have been obtained by mathematical reactions of [MX2L] (M=Co or Ni, X=Cl or Br) and Pb(SC6F5)2. The reaction of pentacoordinate [CoCl(Ph2PCH2CH2PPh2)2]+ and the lead salt yields [CoCl2L] and [Co(SC6F5)2L]. Magnetic moments, u.v. data (both in solution and solid state) and the crystal and molecular structure of the nickel compound are reported. © 1987 Chapman and Hall Ltd.

Idioma original	Anglès
Pàgines (de-a)	197-199
Revista	Transition Metal Chemistry
Volum	12
DOIs	https://doi.org/10.1007/BF01023527
Estat de la publicació	Publicada - 1 de juny 1987

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10.1007/BF01023527

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Catalá, R. M., Colsa, M. E., Cruz-Garritz, D., Torrens, H., Brianso, J. L., Piniella, J. E., & Germain, G. (1987). Pentafluorothiophenolate derivatives of cobalt(II) and nickel(II). The molecular structure of [Ni(SC<inf>6</inf>F<inf>5</inf>)<inf>2</inf>Ph<inf>2</inf>PCH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>]. Transition Metal Chemistry, 12, 197-199. https://doi.org/10.1007/BF01023527

@article{7cf75a057aae47338c57e3e30d50c3cc,

title = "Pentafluorothiophenolate derivatives of cobalt(II) and nickel(II). The molecular structure of [Ni(SC6F5)2Ph2PCH2CH2PPh2]",

abstract = "The tetrahedral compounds [Co(SC6F5)2L] (L=Ph2P(CH2)nPPh2, n=1, 2 and 3) and the squareplanar compound [Ni(SC6F5)2(PhPCH2CH2PPh2)] have been obtained by mathematical reactions of [MX2L] (M=Co or Ni, X=Cl or Br) and Pb(SC6F5)2. The reaction of pentacoordinate [CoCl(Ph2PCH2CH2PPh2)2]+ and the lead salt yields [CoCl2L] and [Co(SC6F5)2L]. Magnetic moments, u.v. data (both in solution and solid state) and the crystal and molecular structure of the nickel compound are reported. {\textcopyright} 1987 Chapman and Hall Ltd.",

author = "Catal{\'a}, {R. M.} and Colsa, {M. E.} and D. Cruz-Garritz and H. Torrens and Brianso, {J. L.} and Piniella, {J. E.} and G. Germain",

year = "1987",

month = jun,

day = "1",

doi = "10.1007/BF01023527",

language = "English",

volume = "12",

pages = "197--199",

journal = "Transition Metal Chemistry",

issn = "0340-4285",

}

Catalá, RM, Colsa, ME, Cruz-Garritz, D, Torrens, H, Brianso, JL, Piniella, JE & Germain, G 1987, 'Pentafluorothiophenolate derivatives of cobalt(II) and nickel(II). The molecular structure of [Ni(SC<inf>6</inf>F<inf>5</inf>)<inf>2</inf>Ph<inf>2</inf>PCH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>]', Transition Metal Chemistry, vol. 12, pàg. 197-199. https://doi.org/10.1007/BF01023527

Pentafluorothiophenolate derivatives of cobalt(II) and nickel(II). The molecular structure of [Ni(SC<inf>6</inf>F<inf>5</inf>)<inf>2</inf>Ph<inf>2</inf>PCH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>]. / Catalá, R. M.; Colsa, M. E.; Cruz-Garritz, D. et al.
In: Transition Metal Chemistry, Vol. 12, 01.06.1987, pàg. 197-199.

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TY - JOUR

T1 - Pentafluorothiophenolate derivatives of cobalt(II) and nickel(II). The molecular structure of [Ni(SC6F5)2Ph2PCH2CH2PPh2]

AU - Catalá, R. M.

AU - Colsa, M. E.

AU - Cruz-Garritz, D.

AU - Torrens, H.

AU - Brianso, J. L.

AU - Piniella, J. E.

AU - Germain, G.

PY - 1987/6/1

Y1 - 1987/6/1

N2 - The tetrahedral compounds [Co(SC6F5)2L] (L=Ph2P(CH2)nPPh2, n=1, 2 and 3) and the squareplanar compound [Ni(SC6F5)2(PhPCH2CH2PPh2)] have been obtained by mathematical reactions of [MX2L] (M=Co or Ni, X=Cl or Br) and Pb(SC6F5)2. The reaction of pentacoordinate [CoCl(Ph2PCH2CH2PPh2)2]+ and the lead salt yields [CoCl2L] and [Co(SC6F5)2L]. Magnetic moments, u.v. data (both in solution and solid state) and the crystal and molecular structure of the nickel compound are reported. © 1987 Chapman and Hall Ltd.

AB - The tetrahedral compounds [Co(SC6F5)2L] (L=Ph2P(CH2)nPPh2, n=1, 2 and 3) and the squareplanar compound [Ni(SC6F5)2(PhPCH2CH2PPh2)] have been obtained by mathematical reactions of [MX2L] (M=Co or Ni, X=Cl or Br) and Pb(SC6F5)2. The reaction of pentacoordinate [CoCl(Ph2PCH2CH2PPh2)2]+ and the lead salt yields [CoCl2L] and [Co(SC6F5)2L]. Magnetic moments, u.v. data (both in solution and solid state) and the crystal and molecular structure of the nickel compound are reported. © 1987 Chapman and Hall Ltd.

U2 - 10.1007/BF01023527

DO - 10.1007/BF01023527

M3 - Article

SN - 0340-4285

VL - 12

SP - 197

EP - 199

JO - Transition Metal Chemistry

JF - Transition Metal Chemistry

ER -

Pentafluorothiophenolate derivatives of cobalt(II) and nickel(II). The molecular structure of [Ni(SC<inf>6</inf>F<inf>5</inf>)<inf>2</inf>Ph<inf>2</inf>PCH<inf>2</inf>CH<inf>2</inf>PPh<inf>2</inf>]

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