Oxidative addition of allylic carbonates to palladium(0) complexes: Reversibility and isomerization

Christian Amatore, Sophie Gamez, Anny Jutand, Gilbert Meyer, Marcial Moreno-Mañas, Lurdes Morral, Roser Pleixats

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Resum

The oxidative addition of a cyclic allylic carbonate to the palladium(0) complex generated from a [Pd(dba)2]+2PPh3 mixture affords a cationic π-allylpalladium(II) complex with the alkyl carbonate as the counter-anion. This reaction is reversible and proceeds with isomerization of the allylic carbonate at the allylic position. The equilibrium constant has been determined in DMF. The influence of the precursor of the palladium(0) is discussed.
Idioma originalAnglès
Pàgines (de-a)3372-3376
RevistaChemistry - A European Journal
Volum6
Número18
DOIs
Estat de la publicacióPublicada - 15 de set. 2000

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