O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding

Anna Company, Elena V. Rybak-Akimova, Xavier Fontrodona, Miquel Costas, Teodor Parella, Antoni Llobet, Miquel Solà, Diana Lamata, Albert Poater, Lawrence Que

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Resum

Two dicopper(I) complexes containing tertiary N-methylated hexaaza ligands which impose different steric constraints to the Cu ions have been synthesized, and their reactivity toward O2 has been compared with a mononuclear related system, highlighting the importance of cooperative effects between the metal centers in O2 activation. © 2006 American Chemical Society.
Idioma originalAnglès
Pàgines (de-a)5239-5241
RevistaInorganic Chemistry
Volum45
Número14
DOIs
Estat de la publicacióPublicada - 10 de jul. 2006

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