Ortho-CH Activation of Aromatic Ketones, Partially Fluorinated Aromatic Ketones, and Aromatic Imines by a Trihydride-Stannyl-Osmium(IV) Complex

Miguel A. Esteruelas, Agustí Lledós, Montserrat Oliván, Enrique Oñate, María A. Tajada, Gregori Ujaque

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Resum

Ortho-CH activation of aromatic ketones, partially fluorinated aromatic ketones, and aromatic imines was investigated using a trihydride-stannyl-osmium(IV) complex. The reaction pathway for the formation of intermediate was evaluated by density functional theory (DFT). The results indicate that the formed products are classical dihydrides and that there is no interactions between the tin atom and any of the hydride ligands.
Idioma originalEnglish
Pàgines (de-a)3753-3765
RevistaOrganometallics
Volum22
Número18
DOIs
Estat de la publicacióPublicada - 1 de set. 2003

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