TY - JOUR
T1 - On the Use of Thermodynamic Cycles for the Calculation of Standard Potentials for the Oxidation of Solid Metals in Solution
AU - Funes-Ardoiz, Ignacio
AU - Maseras, Feliu
PY - 2019/1/7
Y1 - 2019/1/7
N2 - © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The performance of a thermodynamic cycle for the calculation of the standard reduction potential (SRP) of a series of metals is examined. It is found that the introduction of simple entropic corrections substantially improves the agreement with experimental data. The accuracy of the estimations is in the range of 0.04 V, which opens the possibility to calculate the SRP for metals in non-aqueous solvents or other unusual situations.
AB - © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim The performance of a thermodynamic cycle for the calculation of the standard reduction potential (SRP) of a series of metals is examined. It is found that the introduction of simple entropic corrections substantially improves the agreement with experimental data. The accuracy of the estimations is in the range of 0.04 V, which opens the possibility to calculate the SRP for metals in non-aqueous solvents or other unusual situations.
KW - entropy
KW - free energy
KW - redox chemistry
KW - standard reduction potential
KW - thermodynamic cycle
UR - http://www.mendeley.com/research/thermodynamic-cycles-calculation-standard-potentials-oxidation-solid-metals-solution
UR - https://www.scopus.com/pages/publications/85056638478
U2 - 10.1002/cphc.201800877
DO - 10.1002/cphc.201800877
M3 - Article
C2 - 30421482
SN - 1439-4235
VL - 20
SP - 159
EP - 162
JO - ChemPhysChem
JF - ChemPhysChem
ER -