Novel [1n]-meta-heterophane frameworks with a bis-betaine nature

E. Alcalde; C. Ayala; I. Dinarès; N. Mesquida; F. Sánchez-Ferrando

doi:10.1021/jo005678b

Novel [1_n]-meta-heterophane frameworks with a bis-betaine nature

E. Alcalde, C. Ayala, I. Dinarès, N. Mesquida, F. Sánchez-Ferrando

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13 Cites (Scopus)

Resum

A convergent "5 + 1" and "5 + 3" synthetic strategy allowed the synthesis of the first examples of bis-betaines 2 and 3, a prototype of phanes that incorporate heterocyclic betaines. The structure of the quadrupolar macrocyclic systems 2 and 3 together with the dicationic [16]- and [18] meta-heterophane precursors 5•2X and 6•2X were examined by spectroscopy using 1H and 13C NMR techniques together with 1H-DNMR studies and electrospray ionization mass spectrometry.

Idioma original	Anglès
Pàgines (de-a)	2281-2290
Revista	Journal of Organic Chemistry
Volum	66
Número	7
DOIs	https://doi.org/10.1021/jo005678b
Estat de la publicació	Publicada - 6 d’abr. 2001

Accés al document

10.1021/jo005678b

Altres arxius i enllaços

https://www.scopus.com/pages/publications/0035815134

Com citar-ho

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title = "Novel [1n]-meta-heterophane frameworks with a bis-betaine nature",

abstract = "A convergent {"}5 + 1{"} and {"}5 + 3{"} synthetic strategy allowed the synthesis of the first examples of bis-betaines 2 and 3, a prototype of phanes that incorporate heterocyclic betaines. The structure of the quadrupolar macrocyclic systems 2 and 3 together with the dicationic [16]- and [18] meta-heterophane precursors 5•2X and 6•2X were examined by spectroscopy using 1H and 13C NMR techniques together with 1H-DNMR studies and electrospray ionization mass spectrometry.",

author = "E. Alcalde and C. Ayala and I. Dinar{\`e}s and N. Mesquida and F. S{\'a}nchez-Ferrando",

year = "2001",

month = apr,

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doi = "10.1021/jo005678b",

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journal = "Journal of Organic Chemistry",

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AU - Alcalde, E.

AU - Ayala, C.

AU - Dinarès, I.

AU - Mesquida, N.

AU - Sánchez-Ferrando, F.

PY - 2001/4/6

Y1 - 2001/4/6

N2 - A convergent "5 + 1" and "5 + 3" synthetic strategy allowed the synthesis of the first examples of bis-betaines 2 and 3, a prototype of phanes that incorporate heterocyclic betaines. The structure of the quadrupolar macrocyclic systems 2 and 3 together with the dicationic [16]- and [18] meta-heterophane precursors 5•2X and 6•2X were examined by spectroscopy using 1H and 13C NMR techniques together with 1H-DNMR studies and electrospray ionization mass spectrometry.

AB - A convergent "5 + 1" and "5 + 3" synthetic strategy allowed the synthesis of the first examples of bis-betaines 2 and 3, a prototype of phanes that incorporate heterocyclic betaines. The structure of the quadrupolar macrocyclic systems 2 and 3 together with the dicationic [16]- and [18] meta-heterophane precursors 5•2X and 6•2X were examined by spectroscopy using 1H and 13C NMR techniques together with 1H-DNMR studies and electrospray ionization mass spectrometry.

UR - https://www.scopus.com/pages/publications/0035815134

U2 - 10.1021/jo005678b

DO - 10.1021/jo005678b

M3 - Article

SN - 0022-3263

VL - 66

SP - 2281

EP - 2290

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 7