TY - JOUR
T1 - NMR study of 9-(1-adamantylaminomethyl)-9,10-dihydroanthracene and its β-cyclodextrin complexes
AU - Sánchez, Marta
AU - Parella, Teodor
AU - Cervelló, Enric
AU - Jaime, Carlos
AU - Virgili, Albert
PY - 2000/1/1
Y1 - 2000/1/1
N2 - 9-(1-Adamantylaminomethyl)-9,10-dihydroanthracene was prepared via condensation of adamantylnitrile with the 9-anthryllithium and its hydride reduction. An NMR study confirmed a boat conformation for the central ring, with the substituent of C-9 in a pseudo-axial position. The β-cyclodextrin host-guest complexes of the title compound and of the intermediate imine were studied from three points of view: the modification of chemical shift, the intermolecular NOE and the diffusion coefficients, all of which showed different behaviour. 1-Adamantylamine was used as a model to study the formation of the complex. Copyright © 2000 John Wiley & Sons, Ltd.
AB - 9-(1-Adamantylaminomethyl)-9,10-dihydroanthracene was prepared via condensation of adamantylnitrile with the 9-anthryllithium and its hydride reduction. An NMR study confirmed a boat conformation for the central ring, with the substituent of C-9 in a pseudo-axial position. The β-cyclodextrin host-guest complexes of the title compound and of the intermediate imine were studied from three points of view: the modification of chemical shift, the intermolecular NOE and the diffusion coefficients, all of which showed different behaviour. 1-Adamantylamine was used as a model to study the formation of the complex. Copyright © 2000 John Wiley & Sons, Ltd.
KW - 1 H NMR
KW - Adamantyl
KW - Anthracene
KW - Cyclodextrin
KW - Diffusion
KW - NMR
UR - https://www.scopus.com/pages/publications/0034311749
U2 - 10.1002/1097-458X(200011)38:11<925::AID-MRC751>3.0.CO;2-1
DO - 10.1002/1097-458X(200011)38:11<925::AID-MRC751>3.0.CO;2-1
M3 - Article
SN - 0749-1581
VL - 38
SP - 925
EP - 931
JO - Magnetic Resonance in Chemistry
JF - Magnetic Resonance in Chemistry
IS - 11
ER -