NaAlH<inf>4</inf> confined in ordered mesoporous carbon

Christian Bonatto Minella; Inge Lindemann; Pau Nolis; Anja Kießling; Maria Dolors Baró; Markus Klose; Lars Giebeler; Bernd Rellinghaus; Jürgen Eckert; Ludwig Schultz; Oliver Gutfleisch

doi:10.1016/j.ijhydene.2013.04.103

NaAlH<inf>4</inf> confined in ordered mesoporous carbon

Christian Bonatto Minella, Inge Lindemann, Pau Nolis, Anja Kießling, Maria Dolors Baró, Markus Klose, Lars Giebeler, Bernd Rellinghaus, Jürgen Eckert, Ludwig Schultz, Oliver Gutfleisch

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In this paper we performed a comprehensive investigation of the structural and sorption properties of a 40 wt. % NaAlH4 confined in a ordered mesoporous carbon (OMC, i.e. CMK-3) by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), 23Na{1H} and 27Al{1H} solid-state magic angle spinning-nuclear magnetic resonance (MAS-NMR). This study evidences a remarkable improvement of the sorption kinetics of NaAlH4 due to its existence in nanometer size within the OMC. The pressure composition isotherm (PCI) analysis (for the re-absorption step) of the nanoconfined NaAlH4 would suggest an alteration of its equilibrium thermodynamic properties. Copyright © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

Idioma original	Anglès
Pàgines (de-a)	8829-8837
Revista	International Journal of Hydrogen Energy
Volum	38
DOIs	https://doi.org/10.1016/j.ijhydene.2013.04.103
Estat de la publicació	Publicada - 17 de jul. 2013

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10.1016/j.ijhydene.2013.04.103

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@article{a11de49cc9354cabbe570598d7ac9204,

title = "NaAlH4 confined in ordered mesoporous carbon",

abstract = "In this paper we performed a comprehensive investigation of the structural and sorption properties of a 40 wt. % NaAlH4 confined in a ordered mesoporous carbon (OMC, i.e. CMK-3) by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), 23Na{1H} and 27Al{1H} solid-state magic angle spinning-nuclear magnetic resonance (MAS-NMR). This study evidences a remarkable improvement of the sorption kinetics of NaAlH4 due to its existence in nanometer size within the OMC. The pressure composition isotherm (PCI) analysis (for the re-absorption step) of the nanoconfined NaAlH4 would suggest an alteration of its equilibrium thermodynamic properties. Copyright {\textcopyright} 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.",

keywords = "23 1 Na{ H} magic angle spinning-nuclear magnetic resonance, 27 1 Al{ H} magic angle spinning-nuclear magnetic resonance, Complex hydride, Hydrogen storage, Nanoconfinement, Transmission electron microscopy",

author = "{Bonatto Minella}, Christian and Inge Lindemann and Pau Nolis and Anja Kie{\ss}ling and Bar{\'o}, {Maria Dolors} and Markus Klose and Lars Giebeler and Bernd Rellinghaus and J{\"u}rgen Eckert and Ludwig Schultz and Oliver Gutfleisch",

year = "2013",

month = jul,

day = "17",

doi = "10.1016/j.ijhydene.2013.04.103",

language = "English",

volume = "38",

pages = "8829--8837",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Limited",

}

TY - JOUR

T1 - NaAlH4 confined in ordered mesoporous carbon

AU - Bonatto Minella, Christian

AU - Lindemann, Inge

AU - Nolis, Pau

AU - Kießling, Anja

AU - Baró, Maria Dolors

AU - Klose, Markus

AU - Giebeler, Lars

AU - Rellinghaus, Bernd

AU - Eckert, Jürgen

AU - Schultz, Ludwig

AU - Gutfleisch, Oliver

PY - 2013/7/17

Y1 - 2013/7/17

N2 - In this paper we performed a comprehensive investigation of the structural and sorption properties of a 40 wt. % NaAlH4 confined in a ordered mesoporous carbon (OMC, i.e. CMK-3) by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), 23Na{1H} and 27Al{1H} solid-state magic angle spinning-nuclear magnetic resonance (MAS-NMR). This study evidences a remarkable improvement of the sorption kinetics of NaAlH4 due to its existence in nanometer size within the OMC. The pressure composition isotherm (PCI) analysis (for the re-absorption step) of the nanoconfined NaAlH4 would suggest an alteration of its equilibrium thermodynamic properties. Copyright © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

AB - In this paper we performed a comprehensive investigation of the structural and sorption properties of a 40 wt. % NaAlH4 confined in a ordered mesoporous carbon (OMC, i.e. CMK-3) by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), 23Na{1H} and 27Al{1H} solid-state magic angle spinning-nuclear magnetic resonance (MAS-NMR). This study evidences a remarkable improvement of the sorption kinetics of NaAlH4 due to its existence in nanometer size within the OMC. The pressure composition isotherm (PCI) analysis (for the re-absorption step) of the nanoconfined NaAlH4 would suggest an alteration of its equilibrium thermodynamic properties. Copyright © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

KW - 23 1 Na{ H} magic angle spinning-nuclear magnetic resonance

KW - 27 1 Al{ H} magic angle spinning-nuclear magnetic resonance

KW - Complex hydride

KW - Hydrogen storage

KW - Nanoconfinement

KW - Transmission electron microscopy

U2 - 10.1016/j.ijhydene.2013.04.103

DO - 10.1016/j.ijhydene.2013.04.103

M3 - Article

SN - 0360-3199

VL - 38

SP - 8829

EP - 8837

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

ER -

NaAlH<inf>4</inf> confined in ordered mesoporous carbon

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