Molecular structure of {[Ag<inf>13</inf>(μ-SC<inf>5</inf>H<inf>9</inf>NHMe)<inf>16</inf>]<sup>13+</sup>}<inf>n</inf>, a novel one-dimensional non-molecular silver-thiolate

Isidre Casals, Pilar González-Duarte, Joan Sola, Josep Vives, Mercè Font-Bardia, Xavier Solans

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Resum

The polymeric structure of the {[Ag13(μ-SC5H9NHMe)16]13+}n cation contains Ag10S16 units linked by three silver atoms. Each unit consists of a central Ag6(μ-SR)6 core and two Ag4(μ-SR)4 rings, and comprises digonal, trigonal and tetrahedral silver and doubly- and triply-bridging sulphur atoms. © 1990.
Idioma originalEnglish
Pàgines (de-a)769-771
RevistaPolyhedron
Volum9
Número5
DOIs
Estat de la publicacióPublicada - 1 de gen. 1990

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