Metal complexes in organic synthesis-V1 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

M. Moreno-Mañas; A. Trius

doi:10.1016/S0040-4020(01)98915-X

Metal complexes in organic synthesis-V¹ 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis

M. Moreno-Mañas, A. Trius

Departament de Química

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24 Cites (Scopus)

Resum

Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

Idioma original	Anglès
Pàgines (de-a)	3009-3015
Revista	Tetrahedron
Volum	37
Número	17
DOIs	https://doi.org/10.1016/S0040-4020(01)98915-X
Estat de la publicació	Publicada - 1 de gen. 1981

Accés al document

10.1016/S0040-4020(01)98915-X

Altres arxius i enllaços

https://www.scopus.com/pages/publications/0001375618

Com citar-ho

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title = "Metal complexes in organic synthesis-V1 1 For Part IV, see Ref. 30. Alkylations of pentane-2,4-dione with allylic alcohols under palladium catalysis",

abstract = "Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. {\textcopyright} 1981.",

author = "M. Moreno-Ma{\~n}as and A. Trius",

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AU - Moreno-Mañas, M.

AU - Trius, A.

PY - 1981/1/1

Y1 - 1981/1/1

N2 - Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

AB - Pentane-2,4-dione with allylic alcohols or benzyl alcohol with palladium catalysts gives high yields of C-monoalkylated diketones, arising mainly from reaction at the terminal end of the allyic system for alkyl monosubstituted allyl alcohols. The effect of the catalyst on the alcohols has been evaluated; rearrangements and disproportionations have been observed. © 1981.

UR - https://www.scopus.com/pages/publications/0001375618

U2 - 10.1016/S0040-4020(01)98915-X

DO - 10.1016/S0040-4020(01)98915-X

M3 - Article

SN - 0040-4020

VL - 37

SP - 3009

EP - 3015

JO - Tetrahedron

JF - Tetrahedron

IS - 17