TY - JOUR
T1 - Metal-arene interactions in dialkylbiarylphosphane complexes of copper, silver, gold
AU - Pérez-Galán, Patricia
AU - Delpont, Nicolas
AU - Herrero-Gómez, Elena
AU - Maseras, Feliu
AU - Echavarren, Antonio M.
PY - 2010/5/10
Y1 - 2010/5/10
N2 - Dialkylbiphenylphosphane-Au1 complexes exhibit only weak metalarene interactions with the covering arene ring. However, the contacts in isoleptic Ag1 and Cu1 complexes are shorter than the limiting values of 3.03 Å (Ag1) and 2.83 Å (Cu 1). Strong metal-arene interactions were also found in the two Ag1 aquo complexes and in two acetonitrile-Cu1 complexes with dialkylbiphenylphosphane ligands. Arene-Ag1 complexes with these bulky phosphane ligands show the strongest Ag1-arene bonds known. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
AB - Dialkylbiphenylphosphane-Au1 complexes exhibit only weak metalarene interactions with the covering arene ring. However, the contacts in isoleptic Ag1 and Cu1 complexes are shorter than the limiting values of 3.03 Å (Ag1) and 2.83 Å (Cu 1). Strong metal-arene interactions were also found in the two Ag1 aquo complexes and in two acetonitrile-Cu1 complexes with dialkylbiphenylphosphane ligands. Arene-Ag1 complexes with these bulky phosphane ligands show the strongest Ag1-arene bonds known. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
KW - Arene ligands
KW - Copper
KW - Gold
KW - Phosphanes
KW - Silver
U2 - 10.1002/chem.200903507
DO - 10.1002/chem.200903507
M3 - Article
SN - 0947-6539
VL - 16
SP - 5324
EP - 5332
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
IS - 18
ER -