Resum
We report on the magnetic properties of the complex bimetallic compound [Cr(H2O)(NH3)5][FeCl6] studied by ac magnetic susceptibility and magnetization techniques in the range 1.5-30 K and 0-40 kOe. The crystal structure contains discrete [Cr(H2O)(NH3)5]3+ and [FeCl6]3- ions, held together by ionic forces and by a network of hydrogen bonds. At temperatures below (2.32±0.01) K the compound seems to behave as a noncollinear ferrimagnet. In addition, the experimental H-T magnetic phase diagram has been derived. © 1992.
Idioma original | Anglès |
---|---|
Pàgines (de-a) | 243-245 |
Revista | Journal of Magnetism and Magnetic Materials |
Volum | 114 |
Número | 3 |
DOIs | |
Estat de la publicació | Publicada - 11 d’ag. 1992 |