Ionic and covalent copper(II)-based catalysts for Michael additions. The mechanism

Josep Comelles; Marcial Moreno-Mañas; Elisabet Pérez; Anna Roglans; Rosa M. Sebastián; Adelina Vallribera

doi:10.1021/jo049373z

Ionic and covalent copper(II)-based catalysts for Michael additions. The mechanism

Josep Comelles, Marcial Moreno-Mañas, Elisabet Pérez, Anna Roglans, Rosa M. Sebastián, Adelina Vallribera

Departament de Química

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Resum

Cu(SbF6)2-AdamBox and copper(II) bis-(5-tert- butylsalicylaldehydate) catalyze the Michael addition in neutral media. Mechanistic studies, based on UV-vis, IR, and electrospray ionization mass spectrometry (ESI-MS), suggest that copper enolates of the β-dicarbonyl formed in situ are the active nucleophilic species.

Idioma original	Anglès
Pàgines (de-a)	6834-6842
Revista	Journal of Organic Chemistry
Volum	69
Número	20
DOIs	https://doi.org/10.1021/jo049373z
Estat de la publicació	Publicada - 1 d’oct. 2004

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10.1021/jo049373z

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title = "Ionic and covalent copper(II)-based catalysts for Michael additions. The mechanism",

abstract = "Cu(SbF6)2-AdamBox and copper(II) bis-(5-tert- butylsalicylaldehydate) catalyze the Michael addition in neutral media. Mechanistic studies, based on UV-vis, IR, and electrospray ionization mass spectrometry (ESI-MS), suggest that copper enolates of the β-dicarbonyl formed in situ are the active nucleophilic species.",

author = "Josep Comelles and Marcial Moreno-Ma{\~n}as and Elisabet P{\'e}rez and Anna Roglans and Sebasti{\'a}n, {Rosa M.} and Adelina Vallribera",

year = "2004",

month = oct,

day = "1",

doi = "10.1021/jo049373z",

language = "English",

volume = "69",

pages = "6834--6842",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

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T1 - Ionic and covalent copper(II)-based catalysts for Michael additions. The mechanism

AU - Comelles, Josep

AU - Moreno-Mañas, Marcial

AU - Pérez, Elisabet

AU - Roglans, Anna

AU - Sebastián, Rosa M.

AU - Vallribera, Adelina

PY - 2004/10/1

Y1 - 2004/10/1

N2 - Cu(SbF6)2-AdamBox and copper(II) bis-(5-tert- butylsalicylaldehydate) catalyze the Michael addition in neutral media. Mechanistic studies, based on UV-vis, IR, and electrospray ionization mass spectrometry (ESI-MS), suggest that copper enolates of the β-dicarbonyl formed in situ are the active nucleophilic species.

AB - Cu(SbF6)2-AdamBox and copper(II) bis-(5-tert- butylsalicylaldehydate) catalyze the Michael addition in neutral media. Mechanistic studies, based on UV-vis, IR, and electrospray ionization mass spectrometry (ESI-MS), suggest that copper enolates of the β-dicarbonyl formed in situ are the active nucleophilic species.

U2 - 10.1021/jo049373z

DO - 10.1021/jo049373z

M3 - Article

SN - 0022-3263

VL - 69

SP - 6834

EP - 6842

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 20

ER -

Ionic and covalent copper(II)-based catalysts for Michael additions. The mechanism

Resum

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