Interpretation of Conjugated Oxiranes Behavior Toward Nucleophiles

C. Jaime; R. M. Ortuño; J. Font

doi:10.1021/jo00236a028

Interpretation of Conjugated Oxiranes Behavior Toward Nucleophiles

C. Jaime, R. M. Ortuño, J. Font

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The behavior of conjugated oxiranes toward nucleophiles has been rationalized by means of perturbational theory and MNDO calculations. Metal ion coordination to the oxiranic oxygen seems to be important in the regioselectivity of the 1,2-addition on α,β-epoxy esters. © 1988, American Chemical Society. All rights reserved.

Idioma original	Anglès
Pàgines (de-a)	139-141
Revista	Journal of Organic Chemistry
Volum	53
Número	1
DOIs	https://doi.org/10.1021/jo00236a028
Estat de la publicació	Publicada - 1 de gen. 1988

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@article{ee5f9b1236c94ee098eaa55c9c75a783,

title = "Interpretation of Conjugated Oxiranes Behavior Toward Nucleophiles",

abstract = "The behavior of conjugated oxiranes toward nucleophiles has been rationalized by means of perturbational theory and MNDO calculations. Metal ion coordination to the oxiranic oxygen seems to be important in the regioselectivity of the 1,2-addition on α,β-epoxy esters. {\textcopyright} 1988, American Chemical Society. All rights reserved.",

author = "C. Jaime and Ortu{\~n}o, \{R. M.\} and J. Font",

year = "1988",

month = jan,

day = "1",

doi = "10.1021/jo00236a028",

language = "English",

volume = "53",

pages = "139--141",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "1",

}

TY - JOUR

T1 - Interpretation of Conjugated Oxiranes Behavior Toward Nucleophiles

AU - Jaime, C.

AU - Ortuño, R. M.

AU - Font, J.

PY - 1988/1/1

Y1 - 1988/1/1

N2 - The behavior of conjugated oxiranes toward nucleophiles has been rationalized by means of perturbational theory and MNDO calculations. Metal ion coordination to the oxiranic oxygen seems to be important in the regioselectivity of the 1,2-addition on α,β-epoxy esters. © 1988, American Chemical Society. All rights reserved.

AB - The behavior of conjugated oxiranes toward nucleophiles has been rationalized by means of perturbational theory and MNDO calculations. Metal ion coordination to the oxiranic oxygen seems to be important in the regioselectivity of the 1,2-addition on α,β-epoxy esters. © 1988, American Chemical Society. All rights reserved.

UR - https://www.scopus.com/pages/publications/33845280534

U2 - 10.1021/jo00236a028

DO - 10.1021/jo00236a028

M3 - Article

SN - 0022-3263

VL - 53

SP - 139

EP - 141

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 1

ER -

Interpretation of Conjugated Oxiranes Behavior Toward Nucleophiles

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