Insertion of Carbon Disulfide into Ruthenium—Alkenyl Bonds. Formation of an Alkenedithiocarboxylate Ligand

M. Rosario Torres; Aurea Peraies; Josep Ros

doi:10.1021/om00095a033

Insertion of Carbon Disulfide into Ruthenium—Alkenyl Bonds. Formation of an Alkenedithiocarboxylate Ligand

M. Rosario Torres, Aurea Peraies, Josep Ros

Departament de Química

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CS2reacts with complexes Ru(CO)Cl(HC= CHR)(PPh3)2(R=Ph or t-Bu) to give products Ru(CO)-Cl(S2C(H)C=CHR)(PPh3)2(R = Ph (1) and t-Bu (2)). The Insertion products contain an alkenedithiocarboxylate ligand coordinated through two sulfur atoms. The structure of 1 has been established by an X-ray diffraction study. © 1988, American Chemical Society. All rights reserved.

Idioma original	Anglès
Pàgines (de-a)	1223-1224
Revista	Organometallics
Volum	7
Número	5
DOIs	https://doi.org/10.1021/om00095a033
Estat de la publicació	Publicada - 1 de gen. 1988

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@article{f625b851d5b943c2b5427fb75e749139,

title = "Insertion of Carbon Disulfide into Ruthenium—Alkenyl Bonds. Formation of an Alkenedithiocarboxylate Ligand",

abstract = "CS2reacts with complexes Ru(CO)Cl(HC= CHR)(PPh3)2(R=Ph or t-Bu) to give products Ru(CO)-Cl(S2C(H)C=CHR)(PPh3)2(R = Ph (1) and t-Bu (2)). The Insertion products contain an alkenedithiocarboxylate ligand coordinated through two sulfur atoms. The structure of 1 has been established by an X-ray diffraction study. {\textcopyright} 1988, American Chemical Society. All rights reserved.",

author = "Torres, \{M. Rosario\} and Aurea Peraies and Josep Ros",

year = "1988",

month = jan,

day = "1",

doi = "10.1021/om00095a033",

language = "English",

volume = "7",

pages = "1223--1224",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "5",

}

TY - JOUR

T1 - Insertion of Carbon Disulfide into Ruthenium—Alkenyl Bonds. Formation of an Alkenedithiocarboxylate Ligand

AU - Torres, M. Rosario

AU - Peraies, Aurea

AU - Ros, Josep

PY - 1988/1/1

Y1 - 1988/1/1

N2 - CS2reacts with complexes Ru(CO)Cl(HC= CHR)(PPh3)2(R=Ph or t-Bu) to give products Ru(CO)-Cl(S2C(H)C=CHR)(PPh3)2(R = Ph (1) and t-Bu (2)). The Insertion products contain an alkenedithiocarboxylate ligand coordinated through two sulfur atoms. The structure of 1 has been established by an X-ray diffraction study. © 1988, American Chemical Society. All rights reserved.

AB - CS2reacts with complexes Ru(CO)Cl(HC= CHR)(PPh3)2(R=Ph or t-Bu) to give products Ru(CO)-Cl(S2C(H)C=CHR)(PPh3)2(R = Ph (1) and t-Bu (2)). The Insertion products contain an alkenedithiocarboxylate ligand coordinated through two sulfur atoms. The structure of 1 has been established by an X-ray diffraction study. © 1988, American Chemical Society. All rights reserved.

UR - https://www.scopus.com/pages/publications/0001127510

U2 - 10.1021/om00095a033

DO - 10.1021/om00095a033

M3 - Article

SN - 0276-7333

VL - 7

SP - 1223

EP - 1224

JO - Organometallics

JF - Organometallics

IS - 5

ER -

Insertion of Carbon Disulfide into Ruthenium—Alkenyl Bonds. Formation of an Alkenedithiocarboxylate Ligand

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