Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives

Michel Weïwer; Xavier Chaminade; J. Carles Bayón; Elisabet Duñach

doi:10.1002/ejoc.200601112

Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives

Michel Weïwer, Xavier Chaminade, J. Carles Bayón, Elisabet Duñach

Departament de Química

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InIII triflate-catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

Idioma original	Anglès
Pàgines (de-a)	2464-2469
Revista	European Journal of Organic Chemistry
Número	15
DOIs	https://doi.org/10.1002/ejoc.200601112 https://doi.org/10.1002/chin.200736053
Estat de la publicació	Publicada - 25 de juny 2007

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title = "Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives",

abstract = "InIII triflate-catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. {\textcopyright} Wiley-VCH Verlag GmbH & Co. KGaA, 2007.",

keywords = "Camphene, Hydrothiolation, Indium triflate, Rearrangement, Thioacetylation",

author = "Michel We{\"i}wer and Xavier Chaminade and Bay{\'o}n, {J. Carles} and Elisabet Du{\~n}ach",

year = "2007",

month = jun,

day = "25",

doi = "10.1002/ejoc.200601112",

language = "English",

pages = "2464--2469",

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Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives. / Weïwer, Michel; Chaminade, Xavier; Bayón, J. Carles et al.
In: European Journal of Organic Chemistry, Núm. 15, 25.06.2007, pàg. 2464-2469.

Producció científica: Contribució a revista › Article › Recerca › Avaluat per experts

TY - JOUR

T1 - Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives

AU - Weïwer, Michel

AU - Chaminade, Xavier

AU - Bayón, J. Carles

AU - Duñach, Elisabet

PY - 2007/6/25

Y1 - 2007/6/25

N2 - InIII triflate-catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

AB - InIII triflate-catalysed addition of thiols and thiocarboxylic acids to camphene under mild conditions has allowed the functionalisation of the alkene for the first time, with suppression of the classical rearrangement of the camphene terpene skeleton to isobornane structures. © Wiley-VCH Verlag GmbH & Co. KGaA, 2007.

KW - Camphene

KW - Hydrothiolation

KW - Indium triflate

KW - Rearrangement

KW - Thioacetylation

U2 - 10.1002/ejoc.200601112

DO - 10.1002/ejoc.200601112

M3 - Article

SN - 1434-193X

SP - 2464

EP - 2469

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 15

ER -

Indium triflate-catalysed addition of thio compounds to camphene: A novel route to 2,3,3-trimethyl-2-thiobicyclo[2.2.1]heptane derivatives

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