TY - JOUR
T1 - Formation of 1:1, 2:1, and 2:2 Complexes between Carbonyl Compounds and Titanium Tetrachloride. An ab Initio Study
AU - Branchadell, Vicenç
AU - Oliva, Antonio
PY - 1995/6/1
Y1 - 1995/6/1
N2 - The complexes of formaldehyde, acetaldehyde, and acetone with titanium tetrachloride of stoichiometrics 1:1, 2:1, and 2:2 have been studied with ab initio SCF-MO methods. The competition between the formation of the 2:1 and 2:2 complexes has been analyzed, and the role of the steric effects has been discussed. © 1995, American Chemical Society. All rights reserved.
AB - The complexes of formaldehyde, acetaldehyde, and acetone with titanium tetrachloride of stoichiometrics 1:1, 2:1, and 2:2 have been studied with ab initio SCF-MO methods. The competition between the formation of the 2:1 and 2:2 complexes has been analyzed, and the role of the steric effects has been discussed. © 1995, American Chemical Society. All rights reserved.
UR - https://www.scopus.com/pages/publications/0542394940
U2 - 10.1021/ic00117a010
DO - 10.1021/ic00117a010
M3 - Article
SN - 0020-1669
VL - 34
SP - 3433
EP - 3439
JO - Inorg. Chem.
JF - Inorg. Chem.
IS - 13
ER -