Formation of 1:1, 2:1, and 2:2 Complexes between Carbonyl Compounds and Titanium Tetrachloride. An ab Initio Study

Vicenç Branchadell; Antonio Oliva

doi:10.1021/ic00117a010

Formation of 1:1, 2:1, and 2:2 Complexes between Carbonyl Compounds and Titanium Tetrachloride. An ab Initio Study

Vicenç Branchadell, Antonio Oliva

Departament de Química

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Resum

The complexes of formaldehyde, acetaldehyde, and acetone with titanium tetrachloride of stoichiometrics 1:1, 2:1, and 2:2 have been studied with ab initio SCF-MO methods. The competition between the formation of the 2:1 and 2:2 complexes has been analyzed, and the role of the steric effects has been discussed. © 1995, American Chemical Society. All rights reserved.

Idioma original	English
Pàgines (de-a)	3433-3439
Revista	Inorg. Chem.
Volum	34
Número	13
DOIs	https://doi.org/10.1021/ic00117a010
Estat de la publicació	Publicada - 1 de juny 1995

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10.1021/ic00117a010

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title = "Formation of 1:1, 2:1, and 2:2 Complexes between Carbonyl Compounds and Titanium Tetrachloride. An ab Initio Study",

abstract = "The complexes of formaldehyde, acetaldehyde, and acetone with titanium tetrachloride of stoichiometrics 1:1, 2:1, and 2:2 have been studied with ab initio SCF-MO methods. The competition between the formation of the 2:1 and 2:2 complexes has been analyzed, and the role of the steric effects has been discussed. {\textcopyright} 1995, American Chemical Society. All rights reserved.",

author = "Vicen{\c c} Branchadell and Antonio Oliva",

year = "1995",

month = jun,

day = "1",

doi = "10.1021/ic00117a010",

language = "English",

volume = "34",

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TY - JOUR

T1 - Formation of 1:1, 2:1, and 2:2 Complexes between Carbonyl Compounds and Titanium Tetrachloride. An ab Initio Study

AU - Branchadell, Vicenç

AU - Oliva, Antonio

PY - 1995/6/1

Y1 - 1995/6/1

N2 - The complexes of formaldehyde, acetaldehyde, and acetone with titanium tetrachloride of stoichiometrics 1:1, 2:1, and 2:2 have been studied with ab initio SCF-MO methods. The competition between the formation of the 2:1 and 2:2 complexes has been analyzed, and the role of the steric effects has been discussed. © 1995, American Chemical Society. All rights reserved.

AB - The complexes of formaldehyde, acetaldehyde, and acetone with titanium tetrachloride of stoichiometrics 1:1, 2:1, and 2:2 have been studied with ab initio SCF-MO methods. The competition between the formation of the 2:1 and 2:2 complexes has been analyzed, and the role of the steric effects has been discussed. © 1995, American Chemical Society. All rights reserved.

U2 - 10.1021/ic00117a010

DO - 10.1021/ic00117a010

M3 - Article

SN - 0020-1669

VL - 34

SP - 3433

EP - 3439

JO - Inorg. Chem.

JF - Inorg. Chem.

IS - 13

ER -

Formation of 1:1, 2:1, and 2:2 Complexes between Carbonyl Compounds and Titanium Tetrachloride. An ab Initio Study

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