Fluorous aryl compounds by Matsuda-Heck reaction

Jordi Salabert, Rosa María Sebastián, Adelina Vallribera, Anna Roglans, Carmen Nájera

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Fluorous aryl compounds are obtained through the arylation of different electron-rich and electron-poor olefins with an arenediazonium salt bearing a fully fluorinated octyl-ponytail at the para position. The Matsuda-Heck reactions are catalyzed by Pd(OAc)2 or 4-hydroxyacetophenone oxime-derived palladacycle as efficient sources of Pd nanoparticles, with loadings of 1 mol % Pd, at room temperature, in methanol and without the need to add external base. © 2011 Elsevier Ltd. All rights reserved.
Idioma originalEnglish
Pàgines (de-a)8659-8664
Estat de la publicacióPublicada - 11 de nov. 2011


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