Resum
© 2016 E. Schweizerbart'sche Verlagsbuchhandlung, D-70176 Stuttgart. Chladniite, a complex phosphate species belonging to the fillowite group so far only found in meteorites, was identified in a pegmatite from Córdoba (Argentina) as inclusions in beusite. Applying synchrotron through-the-substrate microdiffraction technique to polished thin sections prepared on very thin glass-substrates (0.1 mm), diffraction data with nearly single-crystal quality were directly measured at selected chladniite microvolumes of the section. Chladniite is trigonal (space group R3), with a = 15.0133(3) Å, c = 42.887(2) Å, V = 8371.6(5)Å3. The subsequent crystal-structure refinement confirms that the accuracy attainable by using 0.1-mmthick glass-substrates is comparable to that of routine single-crystal measurements [R1 = 3.34% for 1617 unique reflections]. The refined crystal structure of pegmatitic chladniite differs from the meteoritic one in the cation ordering (Mg, Fe+Mn and Ca) at the various metal sites, with Mn being dominant at the M(1) position.
Idioma original | English |
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Pàgines (de-a) | 287-293 |
Revista | European Journal of Mineralogy |
Volum | 29 |
Número | 2 |
DOIs | |
Estat de la publicació | Publicada - 1 de gen. 2017 |