First Heck reaction with arenediazonium cations with recovery of Pd-triolefinic macrocyclic catalyst

Judit Masllorens, Marcial Moreno-Mañas, Anna Pla-Quintana, Anna Roglans

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Resum

(Matrix presented) The air- and moisture-stable phosphine-free palladium(0) complex 1 is a highly active and recoverable catalyst for Heck olefination of aryl diazonium tetrafluoroborates. The reactions were performed under aerobic conditions at room temperature to give the coupling products in excellent yields.
Idioma originalAnglès
Pàgines (de-a)1559-1561
RevistaOrganic Letters
Volum5
Número9
DOIs
Estat de la publicacióPublicada - 1 de maig 2003

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