Resum
The bonding characteristics and oxidative addition of germanes and silanes were analyzed. The reaction of GeH 4 and GeH 3Ph with Mo(CO)(PP) 2 (PP=diphosphine) produced germane complex. The complex was characterized by x-ray crystallography, nuclear magnetic resonance (NMR) and infrared (IR) spectroscopy. It was found that the factor that made oxidative addition of Ge-H bond easier than that for Si-H was the relative weakness of the Ge-H bond.
Idioma original | Anglès |
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Pàgines (de-a) | 5307-5323 |
Revista | Organometallics |
Volum | 22 |
Número | 25 |
DOIs | |
Estat de la publicació | Publicada - 8 de des. 2003 |