Ethanol and methanol steam reforming on transition metal catalysts supported on detonation synthesis nanodiamonds for hydrogen production

E. Yu Mironova; A. A. Lytkina; M. M. Ermilova; M. N. Efimov; L. M. Zemtsov; N. V. Orekhova; G. P. Karpacheva; G. N. Bondarenko; D. N. Muraviev; A. B. Yaroslavtsev

doi:10.1016/j.ijhydene.2014.11.082

Ethanol and methanol steam reforming on transition metal catalysts supported on detonation synthesis nanodiamonds for hydrogen production

E. Yu Mironova, A. A. Lytkina, M. M. Ermilova, M. N. Efimov, L. M. Zemtsov, N. V. Orekhova, G. P. Karpacheva, G. N. Bondarenko, D. N. Muraviev, A. B. Yaroslavtsev

Departament de Química

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© 2014 Hydrogen Energy Publications, LLC. All rights reserved. In this paper we report the results obtained by the comparative study of catalytic activity of monometallic (Ni, Cu, Ru, Pt) and bimetallic (Pt-Ni, Pt-Cu, Pt-Ru) catalysts synthesized on a surface of detonation nanodiamond (DND) supports in steam reforming of methanol and ethanol for hydrogen production. All obtained catalysts (M/DND) were characterized by TEM, FTIR spectroscopy, X-ray diffraction. The specific surface area of DND-nanocomposites was also evaluated by using BET technique. The obtained M/DND catalysts demonstrated high activity in methanol and ethanol steam reforming reactions. It has been shown that the most active monometallic catalyst is ruthenium one, while Pt-Ru catalyst demonstrates the highest activity in comparison with other bimetallic samples.

Idioma original	Anglès
Pàgines (de-a)	3557-3565
Revista	International Journal of Hydrogen Energy
Volum	40
Número	8
DOIs	https://doi.org/10.1016/j.ijhydene.2014.11.082
Estat de la publicació	Publicada - 1 de gen. 2015

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10.1016/j.ijhydene.2014.11.082

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Mironova, E. Y., Lytkina, A. A., Ermilova, M. M., Efimov, M. N., Zemtsov, L. M., Orekhova, N. V., Karpacheva, G. P., Bondarenko, G. N., Muraviev, D. N., & Yaroslavtsev, A. B. (2015). Ethanol and methanol steam reforming on transition metal catalysts supported on detonation synthesis nanodiamonds for hydrogen production. International Journal of Hydrogen Energy, 40(8), 3557-3565. https://doi.org/10.1016/j.ijhydene.2014.11.082

@article{eb837d2a23c3469e9a2b67d9be39fa88,

title = "Ethanol and methanol steam reforming on transition metal catalysts supported on detonation synthesis nanodiamonds for hydrogen production",

abstract = "{\textcopyright} 2014 Hydrogen Energy Publications, LLC. All rights reserved. In this paper we report the results obtained by the comparative study of catalytic activity of monometallic (Ni, Cu, Ru, Pt) and bimetallic (Pt-Ni, Pt-Cu, Pt-Ru) catalysts synthesized on a surface of detonation nanodiamond (DND) supports in steam reforming of methanol and ethanol for hydrogen production. All obtained catalysts (M/DND) were characterized by TEM, FTIR spectroscopy, X-ray diffraction. The specific surface area of DND-nanocomposites was also evaluated by using BET technique. The obtained M/DND catalysts demonstrated high activity in methanol and ethanol steam reforming reactions. It has been shown that the most active monometallic catalyst is ruthenium one, while Pt-Ru catalyst demonstrates the highest activity in comparison with other bimetallic samples.",

keywords = "Ethanol, Hydrogen production, Methanol, Nanodiamond, Noble metal catalysts, Steam reforming",

author = "Mironova, \{E. Yu\} and Lytkina, \{A. A.\} and Ermilova, \{M. M.\} and Efimov, \{M. N.\} and Zemtsov, \{L. M.\} and Orekhova, \{N. V.\} and Karpacheva, \{G. P.\} and Bondarenko, \{G. N.\} and Muraviev, \{D. N.\} and Yaroslavtsev, \{A. B.\}",

year = "2015",

month = jan,

day = "1",

doi = "10.1016/j.ijhydene.2014.11.082",

language = "English",

volume = "40",

pages = "3557--3565",

journal = "International Journal of Hydrogen Energy",

issn = "0360-3199",

publisher = "Elsevier Limited",

number = "8",

}

Mironova, EY, Lytkina, AA, Ermilova, MM, Efimov, MN, Zemtsov, LM, Orekhova, NV, Karpacheva, GP, Bondarenko, GN, Muraviev, DN & Yaroslavtsev, AB 2015, 'Ethanol and methanol steam reforming on transition metal catalysts supported on detonation synthesis nanodiamonds for hydrogen production', International Journal of Hydrogen Energy, vol. 40, núm. 8, pàg. 3557-3565. https://doi.org/10.1016/j.ijhydene.2014.11.082

Ethanol and methanol steam reforming on transition metal catalysts supported on detonation synthesis nanodiamonds for hydrogen production. / Mironova, E. Yu; Lytkina, A. A.; Ermilova, M. M. et al.
In: International Journal of Hydrogen Energy, Vol. 40, Núm. 8, 01.01.2015, pàg. 3557-3565.

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TY - JOUR

T1 - Ethanol and methanol steam reforming on transition metal catalysts supported on detonation synthesis nanodiamonds for hydrogen production

AU - Mironova, E. Yu

AU - Lytkina, A. A.

AU - Ermilova, M. M.

AU - Efimov, M. N.

AU - Zemtsov, L. M.

AU - Orekhova, N. V.

AU - Karpacheva, G. P.

AU - Bondarenko, G. N.

AU - Muraviev, D. N.

AU - Yaroslavtsev, A. B.

PY - 2015/1/1

Y1 - 2015/1/1

N2 - © 2014 Hydrogen Energy Publications, LLC. All rights reserved. In this paper we report the results obtained by the comparative study of catalytic activity of monometallic (Ni, Cu, Ru, Pt) and bimetallic (Pt-Ni, Pt-Cu, Pt-Ru) catalysts synthesized on a surface of detonation nanodiamond (DND) supports in steam reforming of methanol and ethanol for hydrogen production. All obtained catalysts (M/DND) were characterized by TEM, FTIR spectroscopy, X-ray diffraction. The specific surface area of DND-nanocomposites was also evaluated by using BET technique. The obtained M/DND catalysts demonstrated high activity in methanol and ethanol steam reforming reactions. It has been shown that the most active monometallic catalyst is ruthenium one, while Pt-Ru catalyst demonstrates the highest activity in comparison with other bimetallic samples.

AB - © 2014 Hydrogen Energy Publications, LLC. All rights reserved. In this paper we report the results obtained by the comparative study of catalytic activity of monometallic (Ni, Cu, Ru, Pt) and bimetallic (Pt-Ni, Pt-Cu, Pt-Ru) catalysts synthesized on a surface of detonation nanodiamond (DND) supports in steam reforming of methanol and ethanol for hydrogen production. All obtained catalysts (M/DND) were characterized by TEM, FTIR spectroscopy, X-ray diffraction. The specific surface area of DND-nanocomposites was also evaluated by using BET technique. The obtained M/DND catalysts demonstrated high activity in methanol and ethanol steam reforming reactions. It has been shown that the most active monometallic catalyst is ruthenium one, while Pt-Ru catalyst demonstrates the highest activity in comparison with other bimetallic samples.

KW - Ethanol

KW - Hydrogen production

KW - Methanol

KW - Nanodiamond

KW - Noble metal catalysts

KW - Steam reforming

UR - https://www.scopus.com/pages/publications/84923021397

U2 - 10.1016/j.ijhydene.2014.11.082

DO - 10.1016/j.ijhydene.2014.11.082

M3 - Article

SN - 0360-3199

VL - 40

SP - 3557

EP - 3565

JO - International Journal of Hydrogen Energy

JF - International Journal of Hydrogen Energy

IS - 8

ER -

Ethanol and methanol steam reforming on transition metal catalysts supported on detonation synthesis nanodiamonds for hydrogen production

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