Electronic mechanisms associated with bond-stretch isomerism in transition metal complexes

Yves Jean, Agusti Lledos, Jeremy K. Burdett, Roald Hoffmann

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Resum

Two electronic mechanisms are presented which can explain the existence of bond-stretch isomerism in transition metal complexes: the first entails a real level crossing, and the second, best regarded as a second-order Jahn-Teller effect, has links with bond localization problems in allyl anion and benzene.
Idioma originalAnglès
Pàgines (de-a)140-142
RevistaJournal of the Chemical Society D: Chemical Communications
Número2
DOIs
Estat de la publicacióPublicada - 1 de gen. 1988

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