Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

Marcial Moreno-Mañas; Jordi Ribas

doi:10.1016/S0040-4039(00)99415-2

Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

Marcial Moreno-Mañas, Jordi Ribas

Departament de Química

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Resum

A high regioselectivity has been observed in the palladium catalyzed allylation of "soft" nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. © 1989.

Idioma original	Anglès
Pàgines (de-a)	3109-3112
Revista	Tetrahedron Letters
Volum	30
Número	23
DOIs	https://doi.org/10.1016/S0040-4039(00)99415-2
Estat de la publicació	Publicada - 1 de gen. 1989

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10.1016/S0040-4039(00)99415-2

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https://www.scopus.com/pages/publications/0038768215

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@article{56b943ec65ce497d9bd948a173282f5a,

title = "Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes",

abstract = "A high regioselectivity has been observed in the palladium catalyzed allylation of {"}soft{"} nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. {\textcopyright} 1989.",

author = "Marcial Moreno-Ma{\~n}as and Jordi Ribas",

year = "1989",

month = jan,

day = "1",

doi = "10.1016/S0040-4039(00)99415-2",

language = "English",

volume = "30",

pages = "3109--3112",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Limited",

number = "23",

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TY - JOUR

T1 - Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

AU - Moreno-Mañas, Marcial

AU - Ribas, Jordi

PY - 1989/1/1

Y1 - 1989/1/1

N2 - A high regioselectivity has been observed in the palladium catalyzed allylation of "soft" nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. © 1989.

AB - A high regioselectivity has been observed in the palladium catalyzed allylation of "soft" nucleophiles (pentane-2,4-dione and 4-hydroxy-6-methyl-2-pyrone) when both allylic termini have the same steric requirements and different electronic features. © 1989.

UR - https://www.scopus.com/pages/publications/0038768215

U2 - 10.1016/S0040-4039(00)99415-2

DO - 10.1016/S0040-4039(00)99415-2

M3 - Article

SN - 0040-4039

VL - 30

SP - 3109

EP - 3112

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 23

ER -

Electronic effects on the regioselectivity of nucleophilic attacks on π-allylpalladium complexes

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