TY - JOUR
T1 - Efficient synthesis of chiral Δ2-1,3,4-thiadiazolines from α-pinene and verbenone
AU - Sarmiento, Gabriela P.
AU - Rouge, Pablo D.
AU - Fabian, Lucas
AU - Vega, Daniel
AU - Ortuño, Rosa M.
AU - Moltrasio, Graciela Y.
AU - Moglioni, Albertina G.
PY - 2011/11/30
Y1 - 2011/11/30
N2 - The synthesis of chiral cyclobutane 1,3,4-thiadiazoline derivatives starting from (-)-α-pinene and (-)-verbenone was studied. The diastereoisomeric excesses of the products obtained depended strongly upon the starting chiral ketone. The stereochemical assignments of the synthesized compounds were performed by NMR spectroscopy, X-ray analysis, and theoretical calculations. © 2011 Elsevier Ltd. All rights reserved.
AB - The synthesis of chiral cyclobutane 1,3,4-thiadiazoline derivatives starting from (-)-α-pinene and (-)-verbenone was studied. The diastereoisomeric excesses of the products obtained depended strongly upon the starting chiral ketone. The stereochemical assignments of the synthesized compounds were performed by NMR spectroscopy, X-ray analysis, and theoretical calculations. © 2011 Elsevier Ltd. All rights reserved.
UR - https://www.scopus.com/pages/publications/82755190785
U2 - 10.1016/j.tetasy.2011.10.016
DO - 10.1016/j.tetasy.2011.10.016
M3 - Article
SN - 0957-4166
VL - 22
SP - 1924
EP - 1929
JO - Tetrahedron Asymmetry
JF - Tetrahedron Asymmetry
IS - 20-22
ER -