Resum
Both experimental and theoretical studies on the Diels-Alder cycloadditions of dienophiles 1, 2 and 3 to different dienes show that the observed diastereofacial selectivity results from a combination of electronic and steric interactions. The traditional Felkin-Anh mode is not appropriate for these cases. Several new chiral synthetic building blocks have been prepared. © 1992.
Idioma original | Anglès |
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Pàgines (de-a) | 2659-2680 |
Revista | Tetrahedron |
Volum | 48 |
Número | 13 |
DOIs | |
Estat de la publicació | Publicada - 27 de març 1992 |