TY - JOUR
T1 - Detection of platinum dihydride bisphosphine complexes and studies of their reactivity through para-hydrogen-enhanced NMR methods
AU - Godard, Cyril
AU - López-Serrano, Joaquín
AU - Gálvez-López, María Dolores
AU - Roselló-Merino, Marta
AU - Duckett, Simon B.
AU - Khazal, Iman
AU - Lledós, Agustí
AU - Whitwood, Adrian C.
PY - 2008/11/7
Y1 - 2008/11/7
N2 - In-situ NMR studies on the reactions of Pt{CH2 =CHSi(Me) 2}2O)(PCy3) with phosphines, HSiEt3 and - hydrogen or Pt(L)(L′)(Me)2 alone enable the detection of cis-Pt(L)(L′)(H)2 [L = PCy3 and L′ = PCy 2H, PPh3 or PCy3] which then undergo hydride site interchange and H2 reductive elimination on the NMR timescale. Copyright © 2008 John Wiley & Sons, Ltd.
AB - In-situ NMR studies on the reactions of Pt{CH2 =CHSi(Me) 2}2O)(PCy3) with phosphines, HSiEt3 and - hydrogen or Pt(L)(L′)(Me)2 alone enable the detection of cis-Pt(L)(L′)(H)2 [L = PCy3 and L′ = PCy 2H, PPh3 or PCy3] which then undergo hydride site interchange and H2 reductive elimination on the NMR timescale. Copyright © 2008 John Wiley & Sons, Ltd.
KW - EXSY
KW - NMR
KW - Para-hydrogen
KW - Phip-NMR;mechanism
UR - https://www.scopus.com/pages/publications/55249117956
U2 - 10.1002/mrc.2342
DO - 10.1002/mrc.2342
M3 - Article
SN - 0749-1581
VL - 46
JO - Magnetic Resonance in Chemistry
JF - Magnetic Resonance in Chemistry
IS - SUPPL. 1
ER -