Conjugate addition of alcohols to alkynylalkoxycarbene metal (Cr, W) complexes

Francisco Camps; Amadeu Llebaria; Joseph M. Moretó; Susagna Ricart; Josep M. Viñas; Joseph Ros; Ramón Yáñez

doi:10.1016/0022-328X(91)86215-C

Conjugate addition of alcohols to alkynylalkoxycarbene metal (Cr, W) complexes

Francisco Camps, Amadeu Llebaria, Joseph M. Moretó, Susagna Ricart, Josep M. Viñas, Joseph Ros, Ramón Yáñez

Departament de Química

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Resum

Reaction of alkynylakoxycarbene metal (Cr, W) complexes with alcohols gives the corresponding (2-alkoxyalkenyl)alkoxycarbene metal complexes in moderate to good yields. A high degree of stereo-selectivity is found with linear aliphatic alcohols. © 1991.

Idioma original	Anglès
Revista	Journal of Organometallic Chemistry
Volum	401
Número	1-2
DOIs	https://doi.org/10.1016/0022-328X(91)86215-C
Estat de la publicació	Publicada - 8 de gen. 1991

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10.1016/0022-328X(91)86215-C

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@article{f3344f4debca45679ed823dcc4c4686b,

title = "Conjugate addition of alcohols to alkynylalkoxycarbene metal (Cr, W) complexes",

abstract = "Reaction of alkynylakoxycarbene metal (Cr, W) complexes with alcohols gives the corresponding (2-alkoxyalkenyl)alkoxycarbene metal complexes in moderate to good yields. A high degree of stereo-selectivity is found with linear aliphatic alcohols. {\textcopyright} 1991.",

author = "Francisco Camps and Amadeu Llebaria and Moret{\'o}, {Joseph M.} and Susagna Ricart and Vi{\~n}as, {Josep M.} and Joseph Ros and Ram{\'o}n Y{\'a}{\~n}ez",

year = "1991",

month = jan,

day = "8",

doi = "10.1016/0022-328X(91)86215-C",

language = "English",

volume = "401",

number = "1-2",

}

TY - JOUR

T1 - Conjugate addition of alcohols to alkynylalkoxycarbene metal (Cr, W) complexes

AU - Camps, Francisco

AU - Llebaria, Amadeu

AU - Moretó, Joseph M.

AU - Ricart, Susagna

AU - Viñas, Josep M.

AU - Ros, Joseph

AU - Yáñez, Ramón

PY - 1991/1/8

Y1 - 1991/1/8

N2 - Reaction of alkynylakoxycarbene metal (Cr, W) complexes with alcohols gives the corresponding (2-alkoxyalkenyl)alkoxycarbene metal complexes in moderate to good yields. A high degree of stereo-selectivity is found with linear aliphatic alcohols. © 1991.

AB - Reaction of alkynylakoxycarbene metal (Cr, W) complexes with alcohols gives the corresponding (2-alkoxyalkenyl)alkoxycarbene metal complexes in moderate to good yields. A high degree of stereo-selectivity is found with linear aliphatic alcohols. © 1991.

U2 - 10.1016/0022-328X(91)86215-C

DO - 10.1016/0022-328X(91)86215-C

M3 - Article

SN - 0022-328X

VL - 401

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1-2

ER -

Conjugate addition of alcohols to alkynylalkoxycarbene metal (Cr, W) complexes

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