Conformational analysis of 4-aryl-2,2,6,6-tetramethyl-heptane-3,5-diones. Dipole moment determinations and molecular mechanics calculations

Marcial Moreno-Mañas, Mohamed Fathallah, Irmina Hernández-Fuentes, Carlos Jaime, María E. Lloris, Jorge Marquet, María F. Rey-Stolle

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Resum

The dipole moments of the title diketones have been measured and compared with the values calculated by MM2. Both sets of values are in good agreement. The diketones exist (74-94%) in pairs of enantiomeric conformations with angles between both carbonyl dipoles in the range 62-66°. © 1994.
Idioma originalAnglès
Pàgines (de-a)11213-11218
RevistaTetrahedron
Volum50
Número38
DOIs
Estat de la publicacióPublicada - 1 de gen. 1994

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