Complexes of 1-methyl-4-mercaptopiperidine with zinc(II), cadmium(II) and mercury(II) halides

J. C. Bayon; I. Casals; W. Gaete; P. Gonzalez-Duarte; J. Ros

doi:10.1016/S0277-5387(00)80978-X

Complexes of 1-methyl-4-mercaptopiperidine with zinc(II), cadmium(II) and mercury(II) halides

J. C. Bayon, I. Casals, W. Gaete, P. Gonzalez-Duarte, J. Ros

Departament de Química

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Resum

The preparation of a series of complexes formed by 1-methyl-4-mercaptopiperidine (AH) and divalent zinc, cadmium and mercury halides is reported together with some spectral and physical properties. The results of a crystallographic study allows to establish the structure of those of formula [M2(AH)2X4]H2O (M = Zn, Cd, Hg; X = Br, I) consisting of dimers and involving tetrahedral environment with sulphur-bridges for the metal atoms. Polymeric structures are proposed for the complexes of formulae Cd(AH)Cl2 and Hg2Cl4(AH). © 1982.

Idioma original	Anglès
Pàgines (de-a)	157-161
Revista	Polyhedron
Volum	1
Número	2
DOIs	https://doi.org/10.1016/S0277-5387(00)80978-X
Estat de la publicació	Publicada - 1 de gen. 1982

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10.1016/S0277-5387(00)80978-X

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title = "Complexes of 1-methyl-4-mercaptopiperidine with zinc(II), cadmium(II) and mercury(II) halides",

abstract = "The preparation of a series of complexes formed by 1-methyl-4-mercaptopiperidine (AH) and divalent zinc, cadmium and mercury halides is reported together with some spectral and physical properties. The results of a crystallographic study allows to establish the structure of those of formula [M2(AH)2X4]H2O (M = Zn, Cd, Hg; X = Br, I) consisting of dimers and involving tetrahedral environment with sulphur-bridges for the metal atoms. Polymeric structures are proposed for the complexes of formulae Cd(AH)Cl2 and Hg2Cl4(AH). {\textcopyright} 1982.",

author = "Bayon, {J. C.} and I. Casals and W. Gaete and P. Gonzalez-Duarte and J. Ros",

year = "1982",

month = jan,

day = "1",

doi = "10.1016/S0277-5387(00)80978-X",

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TY - JOUR

T1 - Complexes of 1-methyl-4-mercaptopiperidine with zinc(II), cadmium(II) and mercury(II) halides

AU - Bayon, J. C.

AU - Casals, I.

AU - Gaete, W.

AU - Gonzalez-Duarte, P.

AU - Ros, J.

PY - 1982/1/1

Y1 - 1982/1/1

N2 - The preparation of a series of complexes formed by 1-methyl-4-mercaptopiperidine (AH) and divalent zinc, cadmium and mercury halides is reported together with some spectral and physical properties. The results of a crystallographic study allows to establish the structure of those of formula [M2(AH)2X4]H2O (M = Zn, Cd, Hg; X = Br, I) consisting of dimers and involving tetrahedral environment with sulphur-bridges for the metal atoms. Polymeric structures are proposed for the complexes of formulae Cd(AH)Cl2 and Hg2Cl4(AH). © 1982.

AB - The preparation of a series of complexes formed by 1-methyl-4-mercaptopiperidine (AH) and divalent zinc, cadmium and mercury halides is reported together with some spectral and physical properties. The results of a crystallographic study allows to establish the structure of those of formula [M2(AH)2X4]H2O (M = Zn, Cd, Hg; X = Br, I) consisting of dimers and involving tetrahedral environment with sulphur-bridges for the metal atoms. Polymeric structures are proposed for the complexes of formulae Cd(AH)Cl2 and Hg2Cl4(AH). © 1982.

U2 - 10.1016/S0277-5387(00)80978-X

DO - 10.1016/S0277-5387(00)80978-X

M3 - Article

SN - 0277-5387

VL - 1

SP - 157

EP - 161

JO - Polyhedron

JF - Polyhedron

IS - 2

ER -

Complexes of 1-methyl-4-mercaptopiperidine with zinc(II), cadmium(II) and mercury(II) halides

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