TY - JOUR
T1 - Coassembly of Complementary Polyhedral Metal-Organic Framework Particles into Binary Ordered Superstructures
AU - Meng, Lingxin
AU - Fonseca, Javier
AU - Sánchez-Naya, Roberto
AU - Ghadiri, Amir Mohammad
AU - Imaz, Inhar
AU - Maspoch Comamala, Daniel
N1 - Publisher Copyright:
© 2024 The Authors. Published by American Chemical Society.
PY - 2024/7/26
Y1 - 2024/7/26
N2 - Here we report the formation of a 3D NaCl-type binary porous superstructure via coassembly of two colloidal polyhedral metal-organic framework (MOF) particles having complementary sizes, shapes, and charges. We employed a polymeric-attenuated Coulombic self-assembly approach, which also facilitated the coassembly of these MOF particles with spherical polystyrene particles to form 2D binary superstructures. Our results pave the way for using MOFs to create sophisticated superstructures comprising particles of various sizes, shapes, porosities, and chemical compositions.
AB - Here we report the formation of a 3D NaCl-type binary porous superstructure via coassembly of two colloidal polyhedral metal-organic framework (MOF) particles having complementary sizes, shapes, and charges. We employed a polymeric-attenuated Coulombic self-assembly approach, which also facilitated the coassembly of these MOF particles with spherical polystyrene particles to form 2D binary superstructures. Our results pave the way for using MOFs to create sophisticated superstructures comprising particles of various sizes, shapes, porosities, and chemical compositions.
KW - Alloys
KW - Colloidal crystals
KW - Mixtures
KW - Nanocrystals
KW - Superlattices
UR - https://www.scopus.com/pages/publications/85199911815
UR - https://www.mendeley.com/catalogue/161ee9c8-c436-3b24-af78-aa8968bc76b2/
U2 - 10.1021/jacs.4c07194
DO - 10.1021/jacs.4c07194
M3 - Article
C2 - 39058575
SN - 0002-7863
VL - 146
SP - 21225
EP - 21230
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
IS - 31
ER -