TY - JOUR
T1 - Bis(η5-hydropentalenyl)iron
AU - Molins, Elies
AU - Maniukiewicz, Waldemar
AU - Miravitlles, Carlos
AU - Mas, Montse
AU - Manriquez, Juan M.
AU - Chavez, Ivonne
AU - Oelckers, Beatriz
AU - Farran, Joan
AU - Briansó, José Luis
PY - 1996/10/15
Y1 - 1996/10/15
N2 - In the structure of bis[(3a,4,5,6,6a-η)-1-hydropentalenyl]iron, [Fe(C8H7)2], the two pentalene ligands are parallel. The molecules are packed in chains along the a axis and there are no significant intermolecular interactions. The compound shows disorder at the iron position with a 93.3% major and a 6.7% minor component. The structure of the predominant component has been determined. In addition, the double bond in one pentalene ligand is disordered. This confirms the results of a previous spectroscopic 1H NMR study [Katz & Rosenberger (1963). J. Am. Chem. Soc. 85, 2030-2031].
AB - In the structure of bis[(3a,4,5,6,6a-η)-1-hydropentalenyl]iron, [Fe(C8H7)2], the two pentalene ligands are parallel. The molecules are packed in chains along the a axis and there are no significant intermolecular interactions. The compound shows disorder at the iron position with a 93.3% major and a 6.7% minor component. The structure of the predominant component has been determined. In addition, the double bond in one pentalene ligand is disordered. This confirms the results of a previous spectroscopic 1H NMR study [Katz & Rosenberger (1963). J. Am. Chem. Soc. 85, 2030-2031].
U2 - 10.1107/S0108270196005872
DO - 10.1107/S0108270196005872
M3 - Article
SN - 0108-2701
VL - 52
SP - 2414
EP - 2416
JO - Acta Crystallographica Section C: Crystal Structure Communications
JF - Acta Crystallographica Section C: Crystal Structure Communications
IS - 10
ER -