Au(III)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis

Jordi Serra; Teodor Parella; Xavi Ribas

doi:10.1039/c6sc03699f

Au(III)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis

Jordi Serra, Teodor Parella, Xavi Ribas

Servei de Ressonància Magnètica Nuclear (SeRMN)

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© The Royal Society of Chemistry. Au(iii)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C-O and C-N cross coupling catalysis. The crystal structures of cyclometalated neutral and cationic Au(iii) species are described and their key role in 2 electron-redox Au(i)/Au(iii) catalysis in C-O and C-N cross couplings is shown. Nucleophiles compatible with Au-catalyzed cross couplings include aromatic and aliphatic alcohols and amines, as well as water and amides.

Idioma original	Anglès
Pàgines (de-a)	946-952
Revista	Chemical Science
Volum	8
Número	2
DOIs	https://doi.org/10.1039/c6sc03699f
Estat de la publicació	Publicada - 1 de gen. 2017

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10.1039/c6sc03699f

https://ddd.uab.cat/record/186256

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https://www.scopus.com/pages/publications/85011026047

CCDC 1489676: Experimental Crystal Structure Determination
Serra, J. (Creador), Parella, T. (Creador) & Ribas, X. (Creador), Cambridge Crystallographic Data Centre, 2 de jul. 2016
DOI: 10.5517/ccdc.csd.cc1m042v, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc1m042v&sid=DataCite
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title = "Au(III)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis",

abstract = "{\textcopyright} The Royal Society of Chemistry. Au(iii)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C-O and C-N cross coupling catalysis. The crystal structures of cyclometalated neutral and cationic Au(iii) species are described and their key role in 2 electron-redox Au(i)/Au(iii) catalysis in C-O and C-N cross couplings is shown. Nucleophiles compatible with Au-catalyzed cross couplings include aromatic and aliphatic alcohols and amines, as well as water and amides.",

author = "Jordi Serra and Teodor Parella and Xavi Ribas",

year = "2017",

month = jan,

day = "1",

doi = "10.1039/c6sc03699f",

language = "English",

volume = "8",

pages = "946--952",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "2",

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TY - JOUR

T1 - Au(III)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis

AU - Serra, Jordi

AU - Parella, Teodor

AU - Ribas, Xavi

PY - 2017/1/1

Y1 - 2017/1/1

N2 - © The Royal Society of Chemistry. Au(iii)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C-O and C-N cross coupling catalysis. The crystal structures of cyclometalated neutral and cationic Au(iii) species are described and their key role in 2 electron-redox Au(i)/Au(iii) catalysis in C-O and C-N cross couplings is shown. Nucleophiles compatible with Au-catalyzed cross couplings include aromatic and aliphatic alcohols and amines, as well as water and amides.

AB - © The Royal Society of Chemistry. Au(iii)-aryl species have been unequivocally identified as reactive intermediates in oxidant-free C-O and C-N cross coupling catalysis. The crystal structures of cyclometalated neutral and cationic Au(iii) species are described and their key role in 2 electron-redox Au(i)/Au(iii) catalysis in C-O and C-N cross couplings is shown. Nucleophiles compatible with Au-catalyzed cross couplings include aromatic and aliphatic alcohols and amines, as well as water and amides.

UR - https://www.scopus.com/pages/publications/85011026047

U2 - 10.1039/c6sc03699f

DO - 10.1039/c6sc03699f

M3 - Article

SN - 2041-6520

VL - 8

SP - 946

EP - 952

JO - Chemical Science

JF - Chemical Science

IS - 2

ER -

Au(III)-aryl intermediates in oxidant-free C-N and C-O cross-coupling catalysis

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CCDC 1489676: Experimental Crystal Structure Determination

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