Aqua(5,6-dimethyl-1,10-phenanthroline-N,N′)(malonato-O,O′) copper(II) hydrate

Laura Gasque; Rafael Moreno-Esparza; Elies Mollins; José Luis Briansó-Penalva; Lena Ruiz-Ramírez; Gerardo Medina-Dickinson

doi:10.1107/S0108270198009937

Aqua(5,6-dimethyl-1,10-phenanthroline-N,N′)(malonato-O,O′) copper(II) hydrate

Laura Gasque, Rafael Moreno-Esparza, Elies Mollins, José Luis Briansó-Penalva, Lena Ruiz-Ramírez, Gerardo Medina-Dickinson

Departament de Geologia

Producció científica: Contribució a revista › Article › Recerca › Avaluat per experts

14 Cites (Scopus)

Resum

Each copper ion in the title complex, [Cu(C3H2O4)-(C14H12N 2)(H2O)]·H2O, displays a slightly distorted square-pyramidal coordination geometry, where the water molecule is in the apical position and two malonate O atoms and the phenanthroline N atoms define the base. The five-membered chelate ring defined by the phenanthroline molecule and the Cu atom is nearly planar with only slight distortion, while the ring defined by the malonate moiety and the Cu atom displays an envelope conformation. Hydrogen-bond and π-π* interactions define the crystal packing.

Idioma original	Anglès
Pàgines (de-a)	158-160
Revista	Acta Crystallographica Section C: Crystal Structure Communications
Volum	55
Número	2
DOIs	https://doi.org/10.1107/S0108270198009937
Estat de la publicació	Publicada - 15 de febr. 1999

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10.1107/S0108270198009937

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https://www.scopus.com/pages/publications/0000639018

CCDC 130964: Experimental Crystal Structure Determination
Gasque, L. (Creador), Moreno-Esparza, R. (Creador), Mollins, E. (Creador), Briansó-Penalva, J. L. (Col·laborador), Ruiz-Ramírez, L. (Col·laborador) & Medina-Dickinson, G. (Creador), Cambridge Crystallographic Data Centre, 18 de jul. 1999
DOI: 10.5517/cc4d8nf, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc4d8nf&sid=DataCite
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@article{8bd2792701684bb383756ce5ef18de76,

title = "Aqua(5,6-dimethyl-1,10-phenanthroline-N,N′)(malonato-O,O′) copper(II) hydrate",

abstract = "Each copper ion in the title complex, [Cu(C3H2O4)-(C14H12N 2)(H2O)]·H2O, displays a slightly distorted square-pyramidal coordination geometry, where the water molecule is in the apical position and two malonate O atoms and the phenanthroline N atoms define the base. The five-membered chelate ring defined by the phenanthroline molecule and the Cu atom is nearly planar with only slight distortion, while the ring defined by the malonate moiety and the Cu atom displays an envelope conformation. Hydrogen-bond and π-π* interactions define the crystal packing.",

author = "Laura Gasque and Rafael Moreno-Esparza and Elies Mollins and Brians{\'o}-Penalva, \{Jos{\'e} Luis\} and Lena Ruiz-Ram{\'i}rez and Gerardo Medina-Dickinson",

year = "1999",

month = feb,

day = "15",

doi = "10.1107/S0108270198009937",

language = "English",

volume = "55",

pages = "158--160",

number = "2",

}

TY - JOUR

T1 - Aqua(5,6-dimethyl-1,10-phenanthroline-N,N′)(malonato-O,O′) copper(II) hydrate

AU - Gasque, Laura

AU - Moreno-Esparza, Rafael

AU - Mollins, Elies

AU - Briansó-Penalva, José Luis

AU - Ruiz-Ramírez, Lena

AU - Medina-Dickinson, Gerardo

PY - 1999/2/15

Y1 - 1999/2/15

N2 - Each copper ion in the title complex, [Cu(C3H2O4)-(C14H12N 2)(H2O)]·H2O, displays a slightly distorted square-pyramidal coordination geometry, where the water molecule is in the apical position and two malonate O atoms and the phenanthroline N atoms define the base. The five-membered chelate ring defined by the phenanthroline molecule and the Cu atom is nearly planar with only slight distortion, while the ring defined by the malonate moiety and the Cu atom displays an envelope conformation. Hydrogen-bond and π-π* interactions define the crystal packing.

AB - Each copper ion in the title complex, [Cu(C3H2O4)-(C14H12N 2)(H2O)]·H2O, displays a slightly distorted square-pyramidal coordination geometry, where the water molecule is in the apical position and two malonate O atoms and the phenanthroline N atoms define the base. The five-membered chelate ring defined by the phenanthroline molecule and the Cu atom is nearly planar with only slight distortion, while the ring defined by the malonate moiety and the Cu atom displays an envelope conformation. Hydrogen-bond and π-π* interactions define the crystal packing.

UR - https://www.scopus.com/pages/publications/0000639018

U2 - 10.1107/S0108270198009937

DO - 10.1107/S0108270198009937

M3 - Article

SN - 0108-2701

VL - 55

SP - 158

EP - 160

JO - Acta Crystallographica Section C: Crystal Structure Communications

JF - Acta Crystallographica Section C: Crystal Structure Communications

IS - 2

ER -

Aqua(5,6-dimethyl-1,10-phenanthroline-N,N′)(malonato-O,O′) copper(II) hydrate

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CCDC 130964: Experimental Crystal Structure Determination

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